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Present-1994 | 1993-1984 |1983-1974 | 1973-1964 1000. Trost, B. M.; Huang, Z. “Catalytic (3+2) Palladium?Aminoallyl Cycloaddition with Conjugated Dienes” Angew. Chem. Int. Ed. (2019), 58, 6396. 999. Trost, B. M.; Bai, Y.; Bai, W.-J.; Schultz, J. E. “Enantioselective Divergent Synthesis of C19-Oxo Eburnane Alkaloids via Palladium-Catalyzed Asymmetric Allylic Alkylation of an N-Alkyl-?,?-unsaturated Lactam” J. Am. Chem. Soc., (2019), 141, 4811. 998. Trost, B. M.; Gnanamani, E.; Hung, C.-I J.; Kalnmals, C. A. “Synthesis of Chiral, Densely Substituted Pyrrolidones via Phosphine-Catalyzed Cycloisomerization” Org. Lett., (2019), 21, 1890. 997. Trost, B. M.; Nagaraju, A.; Wang, F.; Zuo, Z.; Xu, J.; Hull, K. L. “Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Dihydroquinolinones” Org. Lett., (2019), 21, 1784. 996. Trost, B. M.; Tracy, J. S.; Yusoontorn, T. “Vanadium-Catalyzed Coupling of Allenols with Electrophilic Halide Sources for the Formation of alpha-Halo-alpha’,beta’-unsaturated Ketones” Org. Lett., (2019), 21, 1207. 995. Trost, Barry M.; Tracy, Jacob S. “Vanadium-Catalyzed Synthesis of Geometrically Defined Acyclic Tri- and Tetrasubstituted Olefins from Propargyl Alcohols” ACS Catal., (2019), 9, 1584. 994. Trost, B. M.; Hung, C.-I J.; Gnanamani, E. “Tuning the Reactivity of Ketones through Unsaturation: Construction of Cyclic and Acyclic Quaternary Stereocenters via Zn-ProPhenol Catalyzed Mannich Reactions” ACS Catal., (2019), 9, 1549. 993. Trost, B. M. Gnanamani, E.; Kalnmals, C. A.; Hung, C.-I. J.; Tracy, J. S. “Direct Enantio- and Diastereoselective Vinylogous Addition of Butenolides to Chromones Catalyzed by Zn-ProPhenol” J. Am. Chem. Soc., (2019), 141, 1489. 992. Trost, B. M.; Schultz, J. E. “Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters” Synthesis (2019), 51, 1. 991. Trost, B. M.; Kalnmals, C. A.; Tracy, J. S.; Bai W.-J. “Highly Chemoselective Deprotection of the 2,2,2- 990. Trost, B. M.; Bai, W.-J.; Stivala, C. E.; Hohn, C.; Poock, C.; Heinrich, M.; Xu, S. Rey, J. “Enantioselective Synthesis of des-Epoxy-Amphidinolide N” J. Am. Chem. Soc. (2018), 140, 49, 17316. 989. Trost, B. M.; Huang, Z.; Murhade, G. M. “Catalytic palladium-oxyallyl cycloaddition” Science (2018), 362, 564. 988. Trost, B. M.; Zell, D.; Hohn, C.; Mata, G.; Maruniak, A. “Enantio? and Diastereoselective Synthesis of Chiral Allenes by Palladium?Catalyzed Asymmetric [3+2] Cycloaddition Reactions” Angew. Chem. Int. Ed. (2018), 57, 12916. 987. Trost, B. M.; Gholami, H. “Propene as an Atom-Economical Linchpin for Concise Total Synthesis of Polyenes: Piericidin A” J. Am. Chem. Soc., (2018), 140, 11623. 986. Trost, B. M.; Mata, G. “Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Trimethylenemethane and Fluorinated Ketones” Angew. Chem. Int. Ed. (2018), 57, 12333. 985. Trost, B. M.; Hung, C.-I.; Scharf, M. J. “Direct Catalytic Asymmetric Vinylogous Additions of alpha,beta- and beta,gamma-Butenolides to Polyfluorinated Alkynyl Ketimines” Angew. Chem. Int. Ed. (2018), 57, 11408. 984. Trost, B. M.; Wang, Y. “A Deprotonation Approach to the Unprecedented Amino-Trimethylenemethane Chemistry: Regio, Diastereo, and Enantioselective Synthesis of Complex Amino Cycles” Angew. Chem. Int. Ed. (2018), 57, 11025. 983. Trost, B. M.; Zhang, Lei; Lam, Tom M. “Synthesis of the Aminocyclitol Core of Jogyamycin via an Enantioselective Pd-Catalyzed Trimethylenemethane (TMM) Cycloaddition” Org. Lett. (2018), 20, 3938. 982. Trost, B. M.; Hung, C.-I; Saget, T.; Gnanamani, E. “Branched aldehydes as linchpins for the enantioselective and stereodivergent synthesis of 1,3-aminoalcohols featuring a quaternary stereocentre” Nature Catal. (2018), 523. 981. Trost, B. M.; Kalnmals, C. A. “Sulfones as Synthetic Linchpins: Transition-Metal-Free sp(3)-sp(2) and sp(2)-sp(2) Cross-Couplings Between Geminal Bis(sulfones) and Organolithium Compounds” Chem.-Eur. J. 2018, 24, 9066. 980. Trost, B. M.; Bai, W.-J.; Hohn, C.; Cregg, J. J. “Palladium-Catalyzed Asymmetric Allylic Alkylation of 3-Substituted 1H-Indoles and Tryptophan Derivatives with Vinylcyclopropanes” J. Am. Chem. Soc., (2018), 140, 6710. 979. Trost, B. M.; Tracy, J. S.; Saget, T. “Direct catalytic enantioselective amination of ketones for the formation of tri- and tetrasubstituted stereocenters” Chem. Sci. (2018), 9, 2975. 978. Trost, B. M.; Tracy, Jacob S. “Organic Synthesis. Use of Alkynes as a Key to Innovation in Designing Structure for Function” Israel J. Chem. (2018), 2, 18. 977. Trost, B. M.; Gnanamani, E.; Tracy, J. S.; Kalnmals C. A. “Zn-ProPhenol Catalyzed Enantio- and Diastereoselective Direct Vinylogous Mannich Reactions between ?,?- and ?,?-Butenolides and Aldimines” J. Am. Chem. Soc., (2017), 139, 18198. 976. Trost, B. M.; Li, X. “Pd-catalyzed asymmetric allylic alkylations via C-H activation of N-allyl imines with glycinates” Chem. Sci. (2017), 8, 6815. 975. Trost, B. M.; Gnanamani, E.; Hung, C.-I. “Controlling Regioselectivity in the Enantioselective N-Alkylation of Indole Analogues Catalyzed by Dinuclear Zinc-ProPhenol” Angew. Chem. Int. Ed. (2017), 56, 10451. 974. Trost, B.M.; Tracy, J.S. "Carbon-Nitrogen Bond Formation via the Vanadium Oxo Catalyzed Sigmatropic Functionalization of Allenols" (2017) Org. Lett., 19, 2630 973. Trost, B.M.; Kalnmals, C.A. "Stereoselective Synthesis of Exocyclic Tetrasubstituted Vinyl Halides via Ru-Catalyzed Halotropic Cycloisomerization of 1,6-Haloenynes" (2017) Org. Lett. 19, 2346 972. Trost, B.M.; Cregg, J.J.; Quach, N. "Isomerization of N-Allylamides to Form Geometrically Defined Di-, Tri-, and Tetrasubstituted Enamides" (2017, J. Am. Chem. Soc., 139, 5139. 971. Trost, B.M.; Chan, W.; Malhotra, S. "Development of the Regiodivergent Asymmetric Prenylation of 3-Substituted Oxindoles" (2017) Chem. Eur. J., 23, 4405. 970. Trost, B.M.; Saget, T.; Hung, C.-I. "Efficient Access to Chiral Trisubstituted Aziridines via Catalytic Enantioselective Aza-Darzens Reactions" (2017) Angew. Chem. Int. Ed., 55, 2440. 969. Trost, B.M.; Ryan, M.C. "Indenylmetal Catalysis in Organic Synthesis" (2017) Angew. Chem. Int. Ed., 55, 2862. 968. Trost, B.M.; Sharif, E.U.; Cregg, J.J. "Ru-Catalyzed Sequence for the Synthesis of Cyclic Amido Ethers" (2017) Chem. Sci., 7, 770-774. 967. Trost, B.M.; Knopf, J.D.; Brindle, C.S. "Synthetic Strategies Employed for the Construction of Fostriecin and Related Natural Products" (2016) Chem. Rev., 116, 15035. 966. Trost, B.M.; Masters, J.T.; Le Vaillant, F.L.; Lumb, J.-P. "Synthesis of a 1,3-Bridged Macrobicyclic Enyne via Chemoselective Cycloisomerization Using Palladium-catalyzed Alkyne-Alkyne Coupling" (2016) J. Org. Chem., 81, 10023. 965. Trost, B.M.; Stivala, C.E.; Frandrick, D.R.; Hull, K.L.; Huang, A.; Poock, C.; Kalkofen, R. "Total Synthesis of (-)-lasonolide A" (2016) J. Am. Chem. Soc., 138, 11690. 964. Trost, B.M.; Masters, J.T.; Taft, B.R.; Lumb, J.-P. "Asymmetric Synthesis of Chiral-Alkynyl Carbonyl and Sulfonyl Derivatives via Sequential Palladium and Copper Catalysis" (2016) Chem. Sci., 7, 6217-6231. 963. Trost, B.M.; Ryan, M.C.; Maurer, D. "Development of a Coordinatively Unsaturated Chiral Indenyl-Ruthenium Catalyst" (2016) Org. Lett., 18, 3166. 962. Trost, B.M.; Debien, L. "Re-Orienting Coupling of Organocuprates with Propargyl Electrophiles from SN2' to SN2 with Stereocontrol" (2016) Chem. Sci., 7, 4985. 961. Trost, B.M.; Ryan, M.C.; Rao, M. "Chiral Cyclopentadienylruthenium Sulfoxide Catalysts for Asymmetric Redox Bicycloisomerization" (2016) Beilstein J. Org. Chem., 12, 1136. 960. Trost, B.M.; Saget, T.; Hung, C.-I. "Direct Catalytic Asymmetric Mannich Reactions for the Construction of Quaternary Carbon Stereocenters" (2016) J. Am. Chem. Soc., 138, 3659. 959. Trost, B.M.; Masters, J.T. "Transition Metal-Catalyzed Couplings of Alkynes to 1,3-Enynes: Modern Methods and Synthetic Applications" (2016) Chem. Soc. Rev., 45, 2212-2238. 958. Trost, B.M.; Koester, D.C.; Sharif, E.U. "Ruthenium-Catalyzed Multicomponent Reactions: Access to Silyl-Hydroxy Vinylsilanes, Stereodefined 1,3-Dienes, and Cyclohexenes" Chem. Eur. J. (2016), 22, 2634. 957. Trost, B.M.; Ryan, M.C. "A Ruthenium/Phosphoramidite-catalyzed Asymmetric Interrupted Metallo-Ene Reaction" J. Am. Chem. Soc. (2016) 138, 1981. 956. Trost, B.M.; Hung, C.-I. "Broad Spectrum Enolate Equivalent for Catalytic Chemo-, Diastereo-, and Enantioselective Addition to N-Boc Imines" J. Am. Chem. Soc. (2016) 138, 15940. 955. Trost, B.M.; Saget, T.; Lerchen, A.; Hung, C.-I. "Catalytic Asymmetric Mannich Reactions with Fluorinated Aromatic Ketones: Efficient Acces to Chiral beta-Fluoramines" Angew. Chem. Int. Ed. (2015) 54, 781-784. 954. Trost, B.M.; Koester, D.C.; Herron, A.N. "Stereocontrolled Synthesis of Vinyl Boronates and Vinyl Silanes via an Atom-Economic Ruthenium Catalyzed Alkene-Alkyne Coupling" Angew. Chem. Int. Ed. (2015) 54, 15863. 953. Trost, B.M.; Biannic, B.; Brindle, C.; O'Keefe, B.M.; Hunter, T.; Ngai, M.-Y. "A Highly Convergent Total Synthesis of Leustroducsin B" J. Am. Chem. Soc. (2015), 137, 11594-11597. 952. Trost, B.M.; Debien, L "Palladium-Catalyzed Trimethylenemethane Cycloaddition of Olefins Activated by the Electron-Withdrawing Trifluoromethyl Group" J. Am. Chem. Soc. (2015) 137, 11606-11609. 951. Trost, B.M.; Tracy, J.S. "Contemporaneous Duel Catalysis: Aldol Products from Non-Carbonyl Substrates" Chem. Eur. J. (2015) 21, 15108-15112. 950. Trost, B.M.; Osipov, M. "Recent Advances on the Total Synthesis of the Communesen Alkaloids and Perophoramidine" Chem. Eur. J. (2015) 21, 16318-16343. 949. Trost, B.M. "Metal Catalyzed Allylic Alkylation: Its Development in the Trost Laboratories" Tetrahedron (2015) 71, 5708-5733. 948. Trost, B.M.; Hung J.-I.; Koester, D.; Miller, Y. "Development of non-C2-symmetric ProPhenol Ligands. The Asymmetric Vinylation of N-Boc Imines" Org. Lett. (2015) 17, 3378. 947. Trost, B.M.; Mahapatra, S.; Hansen, M. "Pd Catalyzed C-H Activation of N-Allyl Imines for Regioselective Allylic Alkylations to Substituted Aza-1,3-Dienes" Angew. Chem. Int. Ed. (2015) 53, 6032. 946. Trost, B.M.; Biannic B. "Redox Cycloisomerization Approach to 1,2-Dihydropyridines" Org. Lett. (2015) 17, 1433. 945. Trost, B.M.; Rao, M. "Development of Chiral Sulfoxide Ligands in Asymmetric Catalysis" Angew. Chem. Int. Ed. (2015) 54, 5026. 944. Trost, B.M.; Donckele, E.J.; Thaisrivongs, D.A.; Osipov, M.; Masters, J.T. "A New Class of Non-C2-Symmetric Ligands for Oxidative and Redox-Netral Palladium-Catalyzed Asymmetric Allylic Alkylations of 1,3-Diketones" J. Am. Chem. Soc. (2015) 137, 2776. 943. Trost, B.M.; Cregg, J.J. "Ruthenium Catalyzed Alkene-Alkyne Coupling of Disubstituted Olefins: Application to the Stereoselective Synthesis of Trisubstituted Enecarbamates" J. Am. Chem. Soc. (2015) 137, 620-623. 942. Trost, B.M.; Ryan, M.C.; Rao, M.; Markovic, T.Z. "Construction of Enantioenriched [3.1.0] Bicycles via a Ruthenium-Catalyzed Asymmetric Redox Bicycloisomerization Reaction" J. Am. Chem. Soc. (2014), 136, 17422-17425. 941. Trost, B.M.; Bartlett, M.J. "ProPhenol-Catalyzed Asymmetric Additions by Spontaneously Assembled Dinuclear Main Group Metal Complexes" Accounts Chem. Res. (2014) 688. 940. Trost, B.M.; Bartlett, M.J. "Catalytic Enantioselective Addition of Terminal Alkynes to Carbonyls" Modern Alkyne Chemistry (2015) 201-238. 939. Trost, B.M. "Redox Isomerization of Propargyl Alcohols to Enones" Modern Alkyne Chemistry (2015) 11-25. 938. Trost B.M.; Osipov, M.; Kruger, S.; Zhang, Y. "A Catalytic Asymmetric Total Synthesis of (-)-perophoramidine" Chem. Sci. (2014). 937. Trost, B.M.; Ehmke, V.; O'Keefe, B.M.; Bringley, D.A. "Palladium-catalyzed Dearomative Trimethylenemethane Cycloaddition Reactions" J. Am. Chem. Soc. (2014) 136, 8213. 936. Trost, B.M.; Ehmke, V. "An Approach for Rapid Increase in Molecular Complexity: Atom Economic Routes to Fused Polycyclic Ring Systems" Org. Lett. (2014) 16, 2708. 935. Trost, B.M., Malhotra, S. "An Asymmetric Stereodivergent Strategy Towards Aminocyclitols" Chem. Eur. J. (2014) 20, 8288. 934. Trost, B.M.; Miege, F. "Development of ProPhenol Ligands for the Diastereo- and Enantioselective Synthesis of beta-Hydroxy-alpha-Amino Esters" J. Am. Chem. Soc. (2014) 136, 3016. 933. Trost, B.M.; Masters, J.T.; Lumb, J.-P.; Fateen, D. "Asymmetric Synthesis of Chiral Cycloalkenone Derivatives via Palladium Catalysis" Chem. Sci. (2014) 5, 1354. 932. Trost, B.M.; Stivala, C.E.; Hull, K.L.; Huang, A.; Fandrick, D.R. "A Concise Synthesis of (-)-lasonolide A" J. Am. Chem. Soc. (2014) 136, 88. 931. Trost, B.M. "Catalysis: Unlimited Frontiers - Our Early Personal Journey into the World of Palladium" Topics in Organometallic Chemistry (2013) 44, 1-12. 930. Trost, B.M.; Rao, M.; Dieskau, A. "A Chiral Sulfoxide-Ligated Ruthenium Complex for Asymmetric Catalysis: Enantio- and Regioselective Allylic Substitution" J. Am. Chem. Soc. (2013) 135, 18697. 929. Trost, B.M.; Czabaniuk, L.C. "Structure and Reactivity of Benzyl-Metal Complexes" Angew. Chem. Int. Ed. (2014) 53, 2826. 928. Trost, B.M.; Bringley, D.A.; Zhang, T.; Cramer, N. "Rapid Access to Spirocyclic Oxindole Alkaloids: Applications of the Asymmetric Palladium-Catalyzed [3+2] Trimethylenemethane Cycloaddition" J. Am. Chem. Soc. (2013) 135, 16720. 927. Trost, B.M.; Michaelis, D.J.; Malhotra, S. "Total Synthesis of (-)-18-epipeloruside A: An Alkyne Lingpin Strategy" Org. Lett. (2013) 15, 5274. 926. Trost, B.M.; Bringley, D.A.; O'Keefe, B.M. "Highly Substituted Enantioselective Cyclopentene Derivatives by Palladium-Catalyzed [3+2] Trimethylenemethane Cycloadditions with Disubstituted Nitroalkenes" Org. Lett. (2013) 15, 5630. 925. Trost, B.M.; Michaelis, D.J.; Truica, M.I. "Dinuclear Zinc-Catalyzed Enantioselective alpha-Hydroxyacetate Aldol Reaction with Activated Ester Equivalents" Org. Lett. (2013) 15, 4516. 924. Trost, B.M.; Osipov, M. “Palladium-Catalyzed Asymmetric Construction of Vicinal All-Carbon Quaternary Stereocenters and Its Application to the Synthesis of Cyclotryptamine Alkaloids” Angew. Chem. Int. Ed., (2013), 52, 9176. 923. Trost, B.M.; Czabaniuk, L.C. “Palladium-Catalyzed Asymmetric Benzylation of Azlactones” Chem. Eur. J. (2013) 19, 15210. 922. Hong, X.; Trost, B.M.; Houk, K. “The Mechanism and Origins of Selectivity in Ru(II)-catalyzed Intramolecular (5+2) Cycloadditions and Ene Reactions of Vinylcyclopropanes and Alkynes from Density Functional Theory” J. Am. Chem. Soc., (2013), 135, 6588. 921. Trost, B.M.; Maruniak, A. “Enantioselective Construction of Highly Substituted Vinylidenecyclopentanes by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition Reactions” Angew. Chem. Int. Ed., (2013), 52, 6262. 920. Trost, B.M.; Bringley, D.A. “Enantioselective Synthesis of 2,2-Disubstituted Tetrahydrofurans by Palladium-Catalyzed [3+2] Cycloadditions of Trimethylenemethane with Ketones” Angew. Chem. Int. Ed., (2013), 52, 4466. 919. Trost, B.M.; Lam, T.M.; Herbage, M.A. “Regio- and Enantioselective Synthesis of Pyrrolidines Bearing a Quaternary Center by Palladium-catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane” J. Am. Chem. Soc., (2013), 135, 2459. 918. Trost, B.M.; Masters, J.T.; Burns, A.C “Palladium-catalyzed Asymmetric Allylic Alkylation of 3-Aryloxindoles with Allylidene Dipivalate: A Versatile Enol Pivalate Product” Angew. Chem. Int. Ed., (2013), 52, 2260. 917. Trost, B.M.; Malhotra, S.; Ellerbrock, P. “Exploring the Uniques Reactivity of Diazoesters: A Novel Approach to Chiral B- Amino Acids” Org. Lett., (2013), 15, 440. 916. Trost, B.M.; Thaisrivongs, D.A.; Donckele, E.J. “Palladium-Catalyzed Enantioselective Allylic Alkylation via C-H Activation" Angew. Chem. Int. Ed., (2013), 52, 1563. 915. Trost, B.M.; Kaneko, T.; Anderson, N.G.; Tappertzhofen, C.; Fahr, B. "Total Synthesis of Aeruginosin 98B" J. Am. Chem. Soc., 134, accpt. (2012). 914. Trost, B.M.; Morris, P.J. Sprague, S.J. "Palladium-Catalyzed Diastereo- and Enantioselective Formal [3+2]-Cycloadditions of Substituted Vinylcyclopropanes" J. Am. Chem. Soc., 134, accpt. (2012). 913. Trost, B.M.; Rey, J. "Diastereoselective Formation of Tetrahydrofurans via Pd-AAA: Synthesis of the C13-C29 Subunit of Amphidinolide N" Org. Lett., 14, accpt. (2012). 912. Trost, B.M.; Thaisrivongs, D.A.; Hansmann, M.M. "Tandem Pd(0) and Pd(II)-catalyzed allylic alkylationvia complementary redox cycles" Angew. Chem.Int. Ed., 51, 5034 (2012). 911. Trost, B.M.; Bartlett, M.J.; Weiss, A.H.; Chan, V.S.; von Wangelin, A.J. "Development of Zn-ProPhenol-Catalyzed Asymmetric Alkyne Addition: Synthesis of Chiral Propargyl Alcohols" Chem. Eur. J., 18, accpt. (2012). 910. Trost, B.M.; Quintard, A. "Asymmetric catalytic synthesis of the proposed structure of trocheliophorolide B" Org. Lett., 14, 4698 (2012). 909. Trost, B.M.; Lam, T.M. "Development of Diamidophosphite Ligands and Their Application to the Palladium-Catalyzed Vinyl-Substituted Trimethylenemethane Asymmetric [3+2] Cycloaddition" J. Am. Chem. Soc., 134, 11319 (2012). 908. Trost, B.M. "Catalysis: Unlimited Frontiers - Our Early Personal Journey into the World of Palladium" Top. Organomet. Chem., 44, 1 (2013). 907. Trost, B.M.; Luan, L. "Synthesis of a-allylated a,b-unsaturated carbonyl compounds using vanadium/palladium contemporaneous dual catalysis" Nature Protocols, 7, 1497 (2012). 906. Trost, B.M.; Koller, R.; Schäffner, B. "Enantioselective Synthesis of a-Tertiary Hydroxyketones from Unfunctionalized Ketones via Palladium-Catalyzed Asymmetric Allylic Alkylation of Enolates" Angew. Chem. Int. Ed., 51, 8290 (2012). 905. Trost, B.M.; Quintard, A. "Asymmetric catalytic alkynylation of acetaldehyde and its application to the synthesis of (+)-tetrahydropyrenophorol" Angew. Chem. Int. Ed., 51, 6704 (2012). 904. Trost, B.M.; Osipov, M.; Dong, G. "Palladium-Catalyzed Asymmetric Allylic Alkylation of Electron-Deficient Pyrroles with Meso Electrophiles" Org. Lett., 14, 2254 (2012). 903. Trost, B.M.; Hansmann, M.M.; Thaisrivongs, D.A. "Palladium-Catalyzed Alkylation of 1,4-Dienes by C-H Activation" Angew. Chem. Int. Ed., 51, 4950 (2012). 902. Trost, B.M.; Hirano, K. "Dinuclear Zinc-Catalyzed Highly Stereoselective Synthesis of a-Alkyl-a-Hydroxy Carboxylic Acid Derivatives" Angew. Chem. Int. Ed., 51, 6480 (2012) 901. Trost, B.M.; Hirano, K. "Dinuclear Zinc Catalyzed Asymmetric Spiroannulation Reaction: An Umpolung Strategy for Formation of Alkylated Hydroxyoxindoles" Org. Lett., 14, 2446 (2012). 900. Trost, B.M.; Czabaniuk, L. "Benzylic Phosphates as Electrophiles in the Palladium-Catalyzed Asymmetric Benzylation of Azlactones" J. Am. Chem. Soc., 134, 5778 (2012). 899. Trost, B.M.; Bringley, D.A.; Seng, P.S. "Enantioselective Palladium-Catalyzed [3+2] Cycloadditions of Trimethylenemethane with Nitroalkenes" Org. Lett., 14, 234 (2012). 898. Trost, B.M.; Breder, A.; Kai, B. "Atom-Economic Synthesis of Functionalized Cycloalkanes via Catalytic Redox Cycloisomerization of Propargyl Alcohols" Org. Lett., 14, 1708 (2012). 897. Trost, B.M.; Bartlett, M.J. "Transition-Metal Catalyzed Synthesis of Aspergillide B: An Alkyne Addition Strategy" Org. Lett., 14, 1322 (2012). 896. Trost, B.M.; Silverman, S.M. "Enantioselective Construction of Pyrrolidines by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Imines" J. Am. Chem. Soc., 134, 4941 (2012). 895. Trost, B.M. "Palladium- and Mo-Catalyzed Asymmetric Allylic Alkylation" Org. Proc. Res. Dev., 16, 185 (2012). 894. Trost, B.M.; Burns, A.C.; Bartlett, M.J.; Tautz, T.; Weiss, A.H. "Thionium Ion-mediated Medium-sized Ring Synthesis of Asteriscunolide D" J. Am. Chem. Soc., 134, 1474 (2012). 893. Trost, B.M.; Malhotra, S.; Koschker, P.; Ellerbrock, P. "The Development of the Enantioselective Addition of Ethyl Diazoacetate to Aldehydes: Asymmetric Synthesis of 1,2-Diols" J. Am. Chem. Soc., 134, 2075 (2012). 892. Trost, B.M.; Michaelis, D.J.; Charpentier, J.; Xu, J. "Palladium-Catalyzed Asymmetric Allylic Alkylation of Carboxylic Acid Derivatives: N-Acyloxazolinones as Ester Enolate Equivalents" Angew. Chem. Int. Ed. 51, 204 (2012) 891. Trost, B.M.; Amans, D.; Seganish, W.M.; Chung, C.K. "Total Synthesis of Laulimalide: Assembly of the Fragments and Completion of the Synthesis of the Natural Product and a Potent Analogue" Chem. Eur. J., 18, 2961 (2012). 890. Trost, B.M.; Seganish, W.M.; Chung, C.K.; Amans, D. "Total Synthesis of Laulimalide: Synthesis of the Northern and Southern Fragments" Chem. Eur. J., 18, 2948 (2012). 889. Trost, B.M.; Crawley, M.L. "Enantioselective Allylic Substitutions in Natural Product Synthesis" Top. Organomet. Chem., 38, 321 (2012). 888. Trost, B.M.; Xie, J.; Sieber, J.D. "The Palladium Catalyzed Asymmetric Addition of Oxindoles and Allenes: an Atom-Economical Versatile Method for the Construction of Chiral Indole Alkaloids" J. Am. Chem. Soc., 133, 20611 (2011) 887. Trost, B.M.; Silverman, S.M.; Stambuli, J.P. "Development of an Asymmetric Trimethylenemethane Cycloaddition Reaction: Application in the Enantioselective Synthesis of Highly Substituted Carbocycles" J. Am. Chem. Soc., 133, 19483 (2011) 886. Trost, B.M.; Burns, A.C.; Tautz, T. "Readily-Accessible Chiral Diene Ligands for Rh-Catalyzed Enantioselective Conjugate Additions of Boronic Acids" Org. Lett., 13, 4566 (2011) 885. Trost, B.M.; Thaisrivongs, D.A.; Hartwig, J. “Palladium-Catalyzed Asymmetric Allylic Alkylations of Polynitrogen-Containing Aromatic Heterocycles” J. Am. Chem. Soc., (2011), 133, accpt. 884. Trost, B.M.; Luan, X.; Miller, Y. “Contemporaneous Dual Catalysis: Chemoselective Coupling of Catalytic Vanadium-allenoate and p-Allylpalladium Intermediates” J. Am. Chem. Soc., (2011), 133, accpt. 883. Trost, B.M.; Osipov, M.; Kalb, P.S.J.; Sorum, M. “Acetoxy Meldrum's Acid: A Versatile Acyl Anion Equivalent in the Pd-Catalyzed Asymmetric Allylic Alkylation” Org. Lett., (2011), 13, accpt. 882. Trost, B.M.; Taft, B.R.; Masters, J.T.; Lumb, J.P. “A New Strategy for the Synthesis of Chiral b-Alkynyl Esters via Sequential Palladium and Copper Catalysis” J. Am. Chem. Soc., (2011), 133, accpt. 881. Olson, D.E.; Maruniak, A.; Malhotra, S.; Trost, B.M.; Du Bois, J. “Synthesis and Reactivity of Unique Heterocyclic Structures en route to Substituted Diamines” Org. Lett., (2011), 13, accpt. 880. Trost, B.M.; Miller, J.R.; Hoffman, C.M. Jr. “A Highly Enantio- and Diastereoselective Molybdenum-Catalyzed Asymmetric Allylic Alkylation of Cyanoesters” J. Am. Chem. Soc., (2011), 133, accpt. 879. Trost, B.M.; Bringley, D.A.; Silverman, S.M. “Asymmetric Synthesis of Methylenetetrahydrofurans by Palladium-Catalyzed [3+2] Cycloaddition of Trimethylenemethane with Aldehydes” J. Am. Chem. Soc., (2011), 133, accpt. 878. Trost, B.M.; Yang, H.; Dong, G. “Total Syntheses of Bryostatins. Syntheses of Two Ring-Expanded Bryostatin Analogues and Development of a New-Generation Strategy to Access the C7-C27 Fragment” Chem. Eur. J., (2011), 17, accpt. 877. Trost, B.M.; Yang, H.; Brindle, C.S.; Dong, G. “Atom-Economic and Stereoselective Syntheses of the A- and B-Ring Subunits of the Bryostatins” Chem. Eur. J., (2011), 17, accpt. 876. Trost, B.M.; Frontier, A.J.; Thiel, O.R.; Yang, H.; Dong, G. “Total Synthesis of Bryostatins. Development of Methodology for Atom-Economic and Stereoselective Synthesis of the C-Ring Subunit” Chem. Eur. J., (2011), 17, accpt. 875. Trost, B.M.; Malhotra, S.; Chan, W.H. “Exercising Regiocontrol in Palladium-Catalyzed Asymmetric Prenylations and Geranylations: Unifying Strategy Towards Flustramines A and B” J. Am. Chem. Soc., (2011), 133, accpt. 874. Trost, B.M.; Morris, P.J. “Palladium-Catalyzed Diastereo- and Enantioselective Synthesis of Substituted Cyclopentanes vis a Dynamic Kinetic Asymmetric Formal [3+2] Cycloaddition of Vinyl Cyclopropanes and Alkylidene Azlactones” Angew. Chem. Int. Ed., (2011), 50, accpt. 873. Trost, B.M.; Ngai, M.-Y.; Dong, G. “Ligand-accelerated Enantioselective Propargylation of Aldehydes via Allenylzinc Reagents” Org. Lett., (2011), 13, 1900. 872. Trost, B.M.; Breder, A.; O'Keefe, B.M.; Rao, M.; Franz,, A.W. “Propargyl Alcohols as b-Oxocarbenolide Precursors for the Ruthenium-Catalyzed Cyclopropanation of Unactivated Olefins by Redox Isomerization” J. Am. Chem. Soc., (2011), 133, 4766. 871. Trost, B.M.; O'Boyle, B.M.; Torres, W.; Ameriks, M.K. “Development of a Flexible Strategy Toward FR900482 and the Mitomycins” Chem. Eur. J., (2011), 17, accpt. 870. Trost, B.M.; Schäffner, B.; Osipov, M.; Wilton, D.A.A. “Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of b-ketoesters: An Unusual Counterion Effect” Angew. Chem. Int. Ed., (2011), 50, accpt. 869. Trost, B.M.; Luan, X. “Contemporaneous Dual Catalysis by Coupling Highly Transient Nucleophilic and Electrophilic Intermediates Generated In Situ” J. Am. Chem. Soc., (2011), 133, 1706. 868. Trost, B.M.; Zhang, T. “Development of a Concise Synthesis of (-)-Oseltamivir (Tamiflu®)” Chem. Eur. J., (2011), 17, accpt. 867. Trost, B.M.; Breder, A. “An Atom-Economical Access to b-Heteroarylated Ketones from Propargyl Alcohols via Tandem Ruthenium/Indium Catalysis” Org. Lett., (2011), 13, 398. 866. Trost, B.M.; Lumb, J.P.; Azzarelli, J. “An Atom-Economic Synthesis of Nitrogen Heterocycles from Alkynes” J. Am. Chem. Soc., (2010), 132, 740. 865. Trost, B.M.; Zhang, Y. “Molybdenum-Catalyzed Asymmetric Allylic Alkylation of 3-Alkyloxindoles: Reaction Development and Applications” Chem. Eur. J., (2010), 16, accpt 864. Trost, B.M.; Dong, G. “Total Synthesis of Bryostatin 16 using a Pd-Catalyzed Diyne-Coupling as Macrocyclization Method and Synthesis of C20-epi-Bryostatin 7 as a Potent Anticancer Agent” J. Am. Chem. Soc., (2010), 132, 16403. 863. Trost, B.M.; Osipov, M.; Dong, G. “Palladium-Catalyzed Dynamic Asymmetric Transformations of Vinyl Aziridines with Nitrogen Heterocycles: Rapid Access to Biologically Active Pyrroles and Indoles” J. Am. Chem. Soc., (2010), 132, 15800. 862. Trost, B.M.; Czabaniuk, L.C. “Palladium-Catalyzed Asymmetric Benzylation of 3-Aryl Oxindoles” J. Am. Chem. Soc., (2010), 132, 15534. 861. Trost, B.M.; Nguyen, H.; Koradin, C. “Synthesis of a Tricyclic Core of Rameswaralide” Tetrahedron Lett., (2010), 51, 6232. 860. Trost, B.M. “Atom Economy: A Challenge for Enhanced Synthetic Efficiency” Handbook of Green Chemistry, P. Anastas, C.-J. Li, eds., (2010), accpt.. 859. Trost, B.M.; O'Boyle, B.M.; Hund, D. “Investigation of a Domino-Heck Reaction for the Rapid Synthesis of Bicyclic Natural Products” Chem. Eur. J., (2010), 16, 9772. 858. Trost, Barry M.; Gutierrez, Alicia C.; Ferreira, Eric M. "Differential Reactivities of Enyne Substrates in Ruthenium- and Palladium-Catalyzed Cycloisomerizations to Bi- and Tri-Cyclic Products." Journal of the American Chemical Society (2010), 132, 9206. 857. Trost, Barry M.; Lehr, Konrad; Michaelis, David J.; Xu, Jiayi; Buckl, Andreas K. "Palladium-Catalyzed Asymmetric Allylic Alkylation of 2-Acylimidazoles as Ester Enolate Equivalents." Journal of the American Chemical Society (2010), 132, 8915. 856. Trost, Barry M.; Silverman, Steven M. "Enantioselective Construction of Highly Substituted Pyrrolidines by Palladium Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Ketimines." Journal of the American Chemical Society (2010), 132, 8238. 855. Trost, Barry M.; Zhang, Ting; Sieber, Joshua, D. "Catalytic Asymmetric Allylic Alkylation Employing Heteroatom Nucleophiles: A Powerful Method for C-X Bond Formation." Chemical Science (Organic Chemistry) (2010), 39, 1600. 854. Trost, Barry M.; Chan, Vincent; Yamamoto, Daisuke "Enantioselective ProPhenol-Catalyzed Addition of 1,3-Diynes to Aldehydes to Generate Synthetically Versatile Building Blocks and Diyne Natural Products." Journal of the American Chemical Society (2010), 132, 5522. 853. Trost, Barry M.; Osipov, Maksim; Dong, Guangbin. "A Concise Enantioselective Synthesis of (-)-Ranirestat." Organic Letters (2010), 12, 1276. 852. Trost, Barry M.; Ferreira, Eric M.; Guitierrez, Alicia C. "The Direct Catalytic Asymmetric Aldol Reaction." Chem. Soc. Rev. (2010), 39, 1600. 851. Trost, B.M.; Li, C.J. “Cyclic 1,2-Diketones as Core Building Blocks: A Strategy for the Total Synthesis of (-)-Terpestacin” Chem. Eur. J., (2010), 16, 6265. 850. Trost, Barry M.; Zhang, Yong "Catalytic Double Stereoinduction in Asymmetric Allylic Alkylation of Oxindoles." Chemistry: A European Journal (2010), 16, 296. 849. Trost, Barry M.; Xu, Jiayi; Schmidt, Thomas "Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates." Journal of the American Chemical Society (2009), 131, 18343. 848. Trost, Barry M.; Amans, Dominique; Seganish, W. Michael; Chung, Cheol K. "Evaluating Transition Metal-Catalyzed Transformations for the Synthesis of Laulimalide." Journal of the American Chemical Society (2009), 131, 17087. 847. Trost, Barry M.; O'Boyle, Brendan M.; Hund, Daniel "Total Synthesis and Stereochemical Assignment of (-)-Ushikulide A." Journal of the American Chemical Society (2009), 131, 15066. 846. Trost, Barry M.; Thaisrivongs, David A. "Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylations of 2-Substituted Pyridines." Journal of the American Chemical Society (2009), 131, 12056. 845. Trost, Barry M.; McDougall, Patrick J. "Access to a Welwitindolinone Core Using Sequential Cycloadditions." Organic Letters (2009), 11, 3782. 844. Trost, Barry M.; Brennan, Megan K. "Asymmetric Syntheses of Oxindole and Indole Spirocyclic Alkaloid Natural Products." Synthesis (2009), 3003. 843. Trost, Barry M.; Sieber, Joshua, D.; Qian, Wei; Dhawan, Rajiv; Ball, Zachary, T. "Asymmetric Total Synthesis of Soraphen A: A Flexible Alkyne Strategy." Angewandte Chemie International Edition (2009), 48, 5478-5481. 842. Trost, Barry M.; Zhang, Yong; Zhang, Ting "Direct N-Carbamoylation of 3-Mono-substituted Oxindoles with Alkyl Imidazole Carboxylates." Journal of Organic Chemistry (2009), 74, 5115-5117. 841. Trost, Barry M.; Gutierrez, Alicia C.; Livingston, Robert C. "Tandem Ruthenium-Catalyzed Redox Isomerization-O-Conjugate Addition: An Atom Economic Synthesis of Cyclic Ethers." Organic Letters (2009), 11, 2539-2542. 840. Trost, Barry M.; Dong, Guangbin "A Stereodivergent Strategy to Both Product Enantiomers from the Same Enantiomer of a Stereoinducing Catalyst: Agelastatin A." Chemistry: A European Journal (2009), 15, 6910-6919. 839. Trost, Barry M.; Malhotra, Sushant, M.; Olsen, David E.; Maruniak, Autumn; DuBois, Justin "Asymmetric Synthesis of Diamine Derivatives via Sequential Palladium and Rhodium Catalysis." Journal of the American Chemical Society (2009), 131, 4190. 838. Fu, Q. Shiang; Boonchayaanant, Benjaporn; Tang, Weiping; Trost, Barry M.; Criddle, Craig S. "Simple Menaquinones Reduce Carbon Tetrachloride and Iron (III)." Biodegradation (2009), 109, 20. 837. Trost, Barry M.; Hitce, Julien. "Direct Asymmetric Michael Addition to Nitroalkenes: Vinylogous Nucleophilicity Under Dinuclear Zinc Catalysis." Journal of the American Chemical Society (2009), 131, 4572-4573. 836. Trost, Barry M.; Weiss, Andrew H. "The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups." Advanced Synthesis and Catalysis (2009), in press. 835. Trost, Barry M.; Martos-Redruejo, Alicia "A Regioselective Ru-Catalyzed Alkene-Alkyne Coupling to Form Z,Z-1,3-Dienes." Organic Letters (2009), 11, 1071. 834. Trost, Barry M.; Malhotra, Sushant; Fried, Benj A. "Magnesium-Catalyzed Asymmetric Direct Aldol Addition of Ethyl Diazoacetate to Aromatic, Aliphatic, and a,b-Unsaturated Aldehydes." Journal of the American Chemical Society (2009), 131, 1674. 833. Trost, Barry M.; Bertogg, Andreas "An Unprecedented Si-Based Benzylic 1,4--Rearrangement/Cyclization Reaction." Organic Letters (2009), 11, 511. 832. Trost, Barry, M.; Maulide, Nuno; Rudd, Michael T. "Ruthenium-Catalyzed Cross-Coupling of Tertiary Propargylic Alcohols with w-Alkynenitriles: a Regio- and Stereoselective Surrogate for the Aldol Condensation." Journal of the American Chemical Society (2009), 131, 420. 831. Trost, Barry M.; Xie, Jia; Maulide, Nuno "Stereoselective, Dual-Mode Ruthenium-Catalyzed Ring-Expansion of Alkynylcyclopropanols." Journal of the American Chemical Society (2008), 130, 17258-17259. 830. Trost, Barry M.; Maulide, Nuno; Livingston, Robert C. "A Ruthenium-Catalyzed, Atom-economical Synthesis of Nitrogen Heterocycles." Journal of the American Chemical Society (2008), 130, 16502-16503. 829. Trost, Barry M.; O'Boyle, B.M. "Exploiting Orthogonal Reactive Functionality: Synthesis and Stereochemical Assignment of Ushlikulide A." Journal of he American Chemical Society (2008), 130, 16190-16192. 828. Trost, Barry M.; Ferreira, Eric M.; Gutierrez, Alicia C. "Ruthenium and Palladium-Catalyzed Enyne Cycloisomerizations - Differentially Stereoselective Syntheses of Bicyclic Structures." Journal of the American Chemical Society (2008), 130, 16176. 827. Trost, Barry M.; Waser, Jerome "Total Synthesis of (-)-Pseudolaric Acid." Journal of the American Chemical Society (2008), 130, 16424. 826. Trost, Barry M.; McDougall, Patrick J.; Hartmann, Olaf; Wathen, Peter "Asymmetric Synthesis of Bicyclo[4.3.1] and [3.3.2]-Decadienes via [6+3] Trimethylenemethane Cycloaddition with Tropones." Journal of the American Chemical Society (2008), 130, 14960-14961. 825. Trost, Barry M.; Thaisrivongs, David "A Lewis Acid Strategy for Employing Unstabilized Nucleophiles in Palladium Catalyzed Asymmetric Allylic Alkylations." Journal of the American Chemical Society (2008), 130, 14092-14093. 824. Trost, Barry M.; Dong, Guangbin "Total Synthesis of Bryostatin 16 Using Atom-Economical and Chemoselective Approaches." Nature (2008), 456, 485-488. 823. Trost, Barry M.; McClory, Andrew "Metal Vinylidenes as Catalytic Species in Organic Reactions." Chemistry - An Asian Journal (2008), 3, 164-194. 822. Trost, Barry M.; Zhang, Yong "Mo-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of 3-Aryloxindoles." Journal of the American Chemical Society (2007), 129, 14548-14549. 821. Trost, Barry M.; Waser, Jerome; Meyer, Arndt "Total Synthesis of (-)-Pseudolaric Acid B." Journal of the American Chemical Society (2007), 129, 14556-14557. 820. Trost, Barry M.; Xu, Jiayi "The O-Acylation of Ketone Enolates by Allyl 1H-Imidazole-1-carboxylate Mediated with Boron Trifluoride Etherate-A Convenient Procedure for the Synthesis of Substituted Allyl Enol Carbonates." Journal of Organic Chemistry (2007), 72, 9372-9375. 819. Trost, Barry M.; Silverman, Steven M.; Stambuli, James P. "Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Imines." Journal of the American Chemical Society (2007), 129, 12398. 818. Trost, Barry M.; Cramer, Nicolai; Silverman, Steven M. "Enantioselective Construction of Spirocyclic Oxindolic Cyclopentanes by Palladium-Catalyzed Trimethylenemethane-[3+2]-Cycloaddition." Journal of the American Chemical Society (2007), 129, 12396. 817. Trost, Barry M.; Brennan, Megan K. "Palladium-Catalyzed Regio- and Enantioselective Allylic Alkylation of Bis Allylic Carbonates Derived from Morita-Baylis-Hillman Adducts." Organic Letters (2007), 9, 3961-3964. 816. Trost, Barry M.; Weiss, Andrew H. "An Alkyne Strategy for the Asymmetric Synthesis of Natural Products: Application to (+)-Spirolaxine Methyl Ether." Angewandte Chemie, International Edition (2007), 46, 7808. 815. Trost, Barry M.; Aponick, Aaron; Stanzl, Benjamin N. "A Convergent Pd-Catalyzed Asymmetric Allylic Alkylation of dl- and meso-Divinylethylene Carbonate: Enantioselective Synthesis of (+)-Australine Hydrochloride and Formal Synthesis of Isoaltholactone." Chemistry - A European Journal (2007), 13, 9547-9560. 814. Trost, Barry M.; Hu, Yimin; Horne, Daniel B. "Total Synthesis of (+)-Frondosin A. Application of the Ru-Catalyzed [5+2] Cycloaddition." Jounal of the American Chemical Society (2007), 129, 11781-11790. 813. Trost, Barry M.; Fandrick, Daniel R.; Brodman, Tobias; Stiles, Dylan T. "Dynamic Kinetic Asymmetric Allylic Alkylation of Vinylaziridines with Imide Nucleophiles." Angewandte Chemie, International Edition (2007), 46, 6123. 812. Trost, Barry M.; Stiles, Dylan T. "Total Synthesis of Spirotryprostatin B via Diastereoselective Prenylation." Organic Letters (2007), 9, 2763. 811. Trost, Barry M.; Fandrick, Daniel R. "Palladium-Catalyzed Dynamic Kinetic Asymmetric Allylic Alkylation with the DPPBA Ligands." Aldrichimica Acta (2007), 40, 59-72. 810. Trost, Barry M.; Dong, Guangbin "Asymmetric Annulation Towards Pyrrolopiperazinones: Concise, Enantioselective Syntheses of Pyrrole Alkaloid Natural Products." Organic Letters (2007), 9, 2357. 809. Trost, Barry M.; Lupton, David W. "Dinuclear Zinc Catalyzed Enantioselective Aza-Henry Reaction." Organic Letters (2007), 9, 2023-2026. 808. Trost, Barry M.; Gutierrez, Alicia C. "Ruthenium-Catalyzed Cycloisomerization-6p-Cyclization: A Novel Route to Pyridines." Organic Letters (2007), 9, 1473-1476. 807. Trost, Barry M.; Dong, Guangbin; Vance, Jennifer A. "A Diosphenol-Based Strategy for the Total Synthesis of (-)-Terpestacin." Journal of the American Chemical Society (2007), 129, 4540. 806. Trost, Barry M.; Cramer, Nicolai; Bernsmann, Heiko. "Concise Total Synthesis of (±)-Marcfortine B." Journal of the American Chemical Society (2007), 129, 3086. 805. Trost, Barry M.; Dogra, Kalindi "Synthesis of (-)-∆9-trans-Tetrahydrocannabinol: Stereocontrol via Mo-Catalyzed Asymmetric Allylic Alkylation Reaction." Organic Letters (2007), 9, 861-863. 804. Trost, Barry M.; Yang, Hanbiao; Thiel, Oliver, R.; Frontier, Alison, J.; Brindle, Cheyenne, S. "Synthesis of Ring Expanded Bryostatin Analogue." Journal of the American Chemical Society (2007), 129, 2206. 803. Trost, Barry M.; McClory, Andrew "Rhodium-Catalyzed Cycloisomerization: Formation of Indoles, Benzofurans, and Enol Lactones." Angewandte Chemie, International Edition (2007), 46, 2074. 802. Trost, Barry M.; Xu, Jiayi; Reichle, Markus. "Enantioselective Synthesis of a-Tertiary Hydroxyaldehydes by Palladium-Catalyzed Asymmetric Allylic Alkylation of Enolates." Journal of the American Chemical Society (2007), 129, 282. 801. Trost, Barry M.; Zhang, Ting. "Asymmetric Synthesis of a-Substituted Aldehydes by Pd-Catalyzed Asymmetric Allylic Alkylation-Alkene Isomerization-Claisen Rearrangement." Organic Letters (2006), 8, 6007-6010. 800. Trost, Barry M.; Hisaindee, Soleiman. "A Heterodinuclear Asymmetric Catalyst for Conjugate Additions of a-Hydroxyketones to b-Substituted Nitroalkenes." Organic Letters (2006), 8, 6003-6005. 777. Trost, Barry M.; Jiang, Chunhui; Hammer, Kristin. "Palladium-catalyzed ring opening of isoprene monoxide with nitrogen nucleophiles - asymmetric synthesis of branched amino sugars." Synthesis (2005), 3335-3345. 766. Trost, Barry M.; Yang, Hanbiao; Wuitschik, Georg. "A Ru-Catalyzed Tandem Alkyne-Enone Coupling/Michael Addition: Synthesis of 4-Methylene-2,6-cis-tetrahydropyrans." Organic Letters (2005), 7, 4761-4764 758. "Direct Asymmetric Zn-Aldol Reaction of Methyl Vinyl Ketone and Its Synthetic Applications" Trost, Barry M.; Shin, Seunghoon; Sclafani, Joseph A. J. Am. Chem. Soc. (2005), 127, 8602-8603. 757. "Ruthenium-Catalyzed Diyne Hydrative Cyclization: Synthesis of Substituted 1,3-Diene Synthons" Trost, Barry M.; Huang, Xiaojun. Org. Lett. (2005), 7, 2097-2099. 756. "Addition of metalloid hydrides to alkynes: Hydrometallation with boron, silicon, and tin" Trost, Barry M.; Ball, Zachary T. Synthesis (2005), 6, 853-887. 755. "Syntheses of seven-membered rings: Ruthenium-catalyzed intramolecular [5+2] cycloadditions" Trost, Barry M.; Shen, Hong C.; Horne, Daniel B.; Toste, F. Dean; Steinmetz, Bernhard G.; Koradin, Christopher. Chem., Eur. J. (2005), 11, 2577-2590. 754. "Development of Aliphatic Alcohols as Nucleophiles for Palladium-Catalyzed DYKAT Reactions: Total Synthesis of (+)-Hippospongic Acid A" Trost, Barry M.; Machacek, Michelle R.; Tsui, Hong C. J. Am. Chem. Soc. (2005), 127, 7014-7024. 753. "Synthesis of Allenamides by Copper-Catalyzed Coupling of Allenyl Halides with Amides, Carbamates, and Ureas" Trost, Barry M.; Stiles, Dylan T. Org. Lett. (2005), 7, 2117-2120. 752. "Enantioselective synthesis of cyanohydrins by a novel aluminum catalyst" Trost, Barry M.; Martinez-Sanchez, Silvia. Synlett (2005), 4, 627-630. 751. "Ruthenium-Catalyzed Cycloisomerizations of Diynols" Trost, Barry M.; Rudd, Michael T. J. Am. Chem. Soc. (2005), 127, 4763-4776. 750. "Dinuclear Asymmetric Zn Aldol Additions: Formal Asymmetric Synthesis of Fostriecin" Trost, Barry M.; Frederiksen, Mathias U.; Papillon, Julien P. N.; Harrington, Paul E.; Shin, Seunghoon; Shireman, Brock T. J. Am. Chem. Soc. (2005), 127, 3666-3667. 749. "Total Synthesis of (+)-Allocyathin B2" Trost, Barry M.; Dong, Li; Schroeder, Gretchen M. J. Am. Chem. Soc. (2005), 127, 2844-2845. 748. "Regio- and Enantioselective Pd-Catalyzed Allylic Alkylation of Ketones through Allyl Enol Carbonates" Trost, Barry M.; Xu, Jiayi. J. Am. Chem. Soc. (2005), 127, 2846-2847. 747. "A short and concise asymmetric synthesis of hamigeran B" Trost, Barry M.; Pissot-Soldermann, Carole; Chen, Irwin. Chem., Eur. J. (2005), 11, 951-959. 746. "DYKAT of Vinyl Aziridines: Total Synthesis of (+)-Pseudodistomin D" Trost, Barry M.; Fandrick, Daniel R. Org. Lett. (2005), 7, 823-826. 745. "Palladium-catalyzed asymmetric allylation of prochiral nucleophiles: Synthesis of 3-allyl-3-aryl oxindoles" Trost, Barry M.; Frederiksen, Mathias U. Angew. Chem. Int. Ed. (2004), Volume Date 2005, 44, 308-310. 744. "Palladium-catalyzed asymmetric allylic alkylation of ketone enolates" Trost, Barry M.; Schroeder, Gretchen M. Chem., Eur. J. (2005), Volume Date 2004, 11, 174-184. 743. "Ruthenium-Catalyzed Enyne Cycloisomerizations. Effect of Allylic Silyl Ether on Regioselectivity" Trost, Barry M.; Surivet, Jean-Philippe; Toste, F. Dean. J. Am. Chem. Soc. (2004), 126, 15592-15602. 742. "Regioselectivity Control in a Ruthenium-Catalyzed Cycloisomerization of Diyne-ols" Trost, Barry M.; Rudd, Michael T.; Costa, Moises Gulias; Lee, Philip I.; Pomerantz, Andrew E. Org. Lett. (2004), 6, 4235-4238. 741. "A Flexible Approach toward trans-Fused Polycyclic Tetrahydropyrans. A Synthesis of Prymnesin and Yessotoxin Units" Trost, Barry M.; Rhee, Young Ho. Org. Lett. (2004), 6, 4311-4313. 740. "Synthetic Stitching with Silicon: Geminal Alkylation-Hydroxylation of Alkynyl Carbonyl Compounds" Trost, Barry M.; Ball, Zachary T. J. Am. Chem. Soc. (2004), 126, 13942-13944. 739. "Alkene-Alkyne Coupling as a Linchpin: An Efficient and Convergent Synthesis of Amphidinolide P" Trost, Barry M.; Papillon, Julien P. N. J. Am. Chem. Soc. (2004), 126, 13618-13619. 738. "Natural products synthesis: Stereocontrolled total synthesis of (+)-streptazolin by a palladium-catalyzed reductive diyne cyclization" Trost, Barry M.; Chung, Cheol K.; Pinkerton, Anthony B. Angew. Chem. Int. Ed. (2004), 43, 4327-4329. 737. "Biomimetic Enantioselective Total Synthesis of (-)-Siccanin via the Pd-Catalyzed Asymmetric Allylic Alkylation (AAA) and Sequential Radical Cyclizations" Trost, Barry M.; Shen, Hong C.; Surivet, Jean-Philippe. J. Am. Chem. Soc. (2004), 126, 12565-12579. 736. "Synthesis of Chiral Chromans by the Pd-Catalyzed Asymmetric Allylic Alkylation (AAA): Scope, Mechanism, and Applications" Trost, Barry M.; Shen, Hong C.; Dong, Li; Surivet, Jean-Philippe; Sylvain, Catherine. J. Am. Chem. Soc. (2004), 126, 11966-11983. 735. "Asymmetric allylic alkylation, an enabling methodology" Trost, Barry M. J. Org. Chem. (2004), 69, 5813-5837. 734. "Total synthesis of furaquinocin A, B and E" Thiel, Oliver R.; Trost, Barry M.; Tsui, Hon-Chung. Abstracts of Papers, 228th ACS National Meeting, Philadelphia, PA, United States, August 22-26, 2004 (2004) 733. "New insights into the mechanism of molybdenum-catalyzed asymmetric alkylation" Krska, Shane W.; Hughes, David L.; Reamer, Robert A.; Mathre, David J.; Palucki, Michael; Yasuda, Nobuyoshi; Sun, Yongkui; Trost, Barry M.. Pure and Applied Chemistry (2004), 76, 625-633. 732. "A 'chiral aldehyde' equivalent as a building block towards biologically active targets" Trost, Barry M.; Crawley, Matthew L. Chem., Eur. J. (2004), 10, 2237-2252. 731. "Heterocyclic Chemistry" Trost, Barry M. Monatshefte fuer Chemie (2004), 135, VII. 730. "Asymmetric catalysis: an enabling science" Trost, Barry M. PNAS (2004), 101, 5348-5355. 729. "Asymmetric catalysis" Halpern, Jack; Trost, Barry M. PNAS (2004), 101, 5347. 728. "Pd-Catalyzed Carbonylative Lactamization: A Novel Synthetic Approach to FR900482" Trost, Barry M.; Ameriks, Michael K. Org. Lett. (2004), 6, 1745-1748. 727. "Structure Elucidation of (+)-Amphidinolide A by Total Synthesis and NMR Chemical Shift Analysis." Trost, Barry M.; Harrington, Paul E. J. Am. Chem. Soc.(2004), 126, 5028-5029. 726. "An Asymmetric Synthesis of Hamigeran B via a Pd Asymmetric Allylic Alkylation for Enantiodiscrimination" Trost, Barry M.; Pissot-Soldermann, Carole; Chen, Irwin; Schroeder, Gretchen M. J. Am. Chem. Soc. (2004), 126, 4480-4481. 725. "Direct Catalytic Asymmetric Aldol Additions of Methyl Ynones. Spontaneous Reversal in the Sense of Enantioinduction" Trost, Barry M.; Fettes, Alec; Shireman, Brock T. J. Am. Chem. Soc. (2004), 126, 2660-2661. 724. "5H-Oxazol-4-ones as Building Blocks for Asymmetric Synthesis of a-Hydroxycarboxylic Acid Derivatives" Trost, Barry M.; Dogra, Kalindi; Franzini, Maurizio. J. Am. Chem. Soc. (2004), 126, 1944-1945. 723. "A Formal Synthesis of (-)-Mycalamide A" Trost, Barry M.; Yang, Hanbiao; Probst, Gary D. J. Am. Chem. Soc. (2004), 126, 48-49. 722. "Palladium Catalyzed DYKAT of Vinyl Epoxide: Enantioselective Total Synthesis and Assignment of Configuration of (+)-Broussonetine G" Trost, B.M.; Horne, D.B.; Woltering, M.J. Angew. Chem. Int. Ed. (2003) 42, 5987-5990. 721. "Total Syntheses of Furaquinocin A, B, and E" Trost, B.M.; Thiel, O.R.; Tsui, H.-C.. J. Am. Chem. Soc. (2003), 125, accpt. 720. "On the Diastereoselectivity of Ru-Catalyzed [5 + 2] Cycloadditions" Trost, B. M.; Shen, H. C.; Schulz, T.; Koradin, C.; Schirok, H. Org. Lett. (2003) 5, accpt. 719. "Dynamic Kinetic Asymmetric Cycloadditions of Isocyanates to Vinylaziridines" Trost, B.M.; Fandrick, D.R. J. Am. Chem. Soc. (2003), 125, 11836. 718. "A Theoretical Study on the Mechanism, Regiochemistry, and Stereochemistry of Hydrosilylation Catalyzed by Cationic Ruthenium Complexes" Chung, L.W.; Wu, Y.-D.; Trost, B.M.; Ball, Z.T. J. Am. Chem. Soc. (2003), 125, 11578. 717. "A Mechanistic Dichotomy in Ruthenium-Catalyzed Propargyl Alcohol Reactivity: A Novel Hydrative Diyne Cyclization" Trost, B.M.; Rudd, M.T. J. Am. Chem. Soc. (2003) 125, 11516. 716. "Unusual Effects in the Pd-catalyzed Asymmetric Allylic Alkylations: Synthesis of Chiral Chromans" J. Am. Chem. Soc. (2003) 125, 9276. 715. "Migratory Hydroamination: A Facile Enantioselective Synthesis of Benzomorphans", Trost, B.M.; Tang, W. J. Am. Chem. Soc. (2003), 125, 8744. 714. "Asymmetric Transtion-Metal-Catalyzed Allylic Alkylations. Applications in Total Synthesis", Trost, B.M.; Crawley, M.L. Chem. Rev. (2003), 103, 2921. 713. "A Rh(I)-Catalyzed Cycloisomerization of Homo- and Bis-homopropargylic Alcohols" Trost, B.M.; Rhee, Y.H. J. Am. Chem. Soc. (2003) 125, 7482. 712. "Ruthenium-Catalyzed Vinylsilane Synthesis and Cross-Coupling as a Selective Approach to Alkenes: Benzyldimethylsilyl as a Robust Vinylmetal Functionality", Trost, B.M.; Machacek, M.R.; Ball, Z.T. Org. Lett. (2003) 5, 1895. 711. "The Asymmetric Synthesis of (3S,4R,5S)-3-amino-4,5-O-Isopropylidenedioxycyclopentene", Trost, B.M.; Sorum, M.T. Org. Proc. Res. & Dev. (2003) 7, 432. 710. "Pd-Catalyzed Asymmetric Allylic Alkylation. A Short Route to the Cyclopentyl Core of Viridenomycin", Trost, B.M.; Jiang, C.H. Org. Lett. (2003) 5, 1563. 709. "Ruthenium-Catalyzed Alkyne-Propargyl Alcohol Addition. An Asymmetric Total Synthesis of (+)-Alpha-Kainic Acid", Trost, B.M.; Rudd, M.T. Org. Lett. (2003) 5, 1467. 708. "Atom Economy. Palladium-Catalyzed Formation of Coumarins by Addition of Phenols and Alkynoates via a Net C-H Insertion", Trost, B.M.; Toste, F.D.; Greenman, K. J. Am. Chem. Soc. (2003) 125, 4518. 707. "Palladium-Catalyzed Asymmetric Addition of Pronucleophiles to Allenes", Trost, B.M.; Jakel, C.;; Plietker, B. J. Am. Chem. Soc. (2003) 125, 4438. 706. "Palladium Catalyzed Kinetic and Dynamic Kinetic Asymmetric Transformations of gamma-acyloxybutenolides. Enantioselective Total Synthesis of (+)-Aflatoxin B-1 and B-2a" Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (2003) 125, 3090. 705. "Desymmetrization if Meso 1,3-and 1,4-Diols with a Dinuclear Zinc Asymmetric Catalyst", Trost, B.M.; Mino, T. J. Am. Chem. Soc. (2003) 125, 2410. 704. "Uncensored Exchange of Scientific Results" Cozzarelli, N.R.; Halpern, J.; Allison, J.P.; Andersen, H.C.; Ausubel, F.M. et al. Proc. Nat. Acad. Sci. USA (2003) 100, 1464. 703. "An Enantioselective Biomimetic Total Synthesis of (-)-Siccanin" Trost, B.M.; Shen, H.C.; Surivet, J.P. Angew. Chem. Int. Ed. (2003) 42, 3943. 702. "Regioselective Hydrosiltlation of Propargylic Alcohols: An Aldol Surrogate", Trost, B.M.; Ball, Z.T.; Joge, T. Angew. Chem. Int. Ed. (2003) 42, 3415. 701. "Vanadium-Catalyzed Anti-Selective Additions of Allenols to Imines", Trost, B.M.; Jonasson, C. Angew. Chem. Int. Ed. (2003) 42, 2063. 700. "A Direct Catalytic Asymmetric Mannich-Type Reaction to Syn-Amino Alcohols", Trost, B.M.; Terrell, L. J. Am. Chem. Soc. (2003) 125, 338. 699. "Intramolecular Endo-Dig Hydrosilylation Catalyzed by Ruthenium: Evidence for a New Mechanistic Pathway", Trost, B.M.; Ball, Z.T. J. Am. Chem. Soc. (2003) 125, 30. 698. "Enantioselective Synthesis of (-)-Codeine and (-)-Morphine", Trost, B.M.; Tang, W. J. Am. Chem. Soc. (2002) 124, 14542. 697. "Utilization of Molybdenum and Palladium Catalyzed Dynamic Kinetic Asymmetric Transformations for the Preparation of Tertiary and Quaternary Stereogenic Centers: A Concise Synthesis of Tipranavir", Trost, B.M.; Andersen, N.G. J. Am. Chem. Soc. (2002) 124, 14320. 696. "An Efficient One-Pot Enantio- and Diastereoselective Synthesis of Heterocycles", Trost, B.M.; Machacek, M.R. Angew. Chem. Int. Ed. (2002) 41, 4693. 695. "The Unusual Role of CO Transfer in Molybedum-Catalyzed Asymmetric Alkylations", Krska, S.W.; Hughes, D.L.; Reamer, R.A.; Mathre, D.J.; Sun, Y.; Trost, B.M. J. Am. Chem. Soc. (2002) 124, 12656. 694. "Polymer-supported c2-Symmetric Ligands for Palladium Catalyzed Asymmetric Allylic Alkylation Reactions", Trost, B.M.; Pan, Z.; Zambrano, J.; Kujat, C. Angew. Chem. Int. Ed. (2002) 41, 4691. 693. "Ruthenium-Catalyzed Alkene-Akyne Coupling: Synthesis of the Proposed Structure of Amphidinolide A", Trost, B.M.; Chisholm, J.D.; Wrobleski, S.J.; Jung, M. J. Am. Chem. Soc. (2002) 124, 12420. 692."An Acid Catalyzed Macrolactonization Protocol", Trost, B.M.; Chisholm, J.D. Org. Lett. (2002) 4, 3743. 691. "DYKAT of Baylis-Hillman Adducts: Concise Total Synthesis of Furaquinocin E", Trost, B.M.; Thiel, O.R.; Tsui, H.-C. J. Am. Chem. Soc. (2002) 124, 11616. . 690. "Intramolecular Palladium-Catalyzed Allylic Alkylation: Enantio- and Diastereoselective Synthesis of [2.2.2]-Bicycles",Trost, B.M.; Sacchi, K.; Schroeder, G.M.; Asakawa, N. Org. Lett. (2002) 4, 3427. 689. "Stereocontrolled Synthesis of (+)-Boronolide", Trost, B.M.; Yeh, V.S.C. Org. Lett.(2002) 4, 3513. 688. "Palladium Catalyzed Asymmetric Allylic Alkylation of a-Aryl Ketones", Trost, B.M.; Schroeder, G.M.; Kristensen, J. Angew. Chem. Int. Ed. (2002) 41, 3492. 687. "4-Aryloxybutenolides as "Chiral Aldehyde" Building Blocks. An Efficient Enantioselective Total Synthesis of (+)-Brefeldin A", Trost, B.M.; Crawley, M.L. J. Am. Chem. Soc. (2002) 124, 9328. 686. "A Chemoselective Reduction of Alkynes to E-Alkenes", Trost, B.M.; Ball, Z.T.; Jõge, T. J. Am. Chem. Soc. (2002) 124, 7922. 685. "Callipeltoside A: Total Synthesis, Assignment of the Absolute and Relative Configuration, and Evaluation of Synthetic Analogs",Trost, B.M.; Gunzner, J.L.; Dirat, O.; Rhee, Y.-H. J. Am. Chem. Soc. (2002) 124, 10396. 684. "An Efficient Asymmetric Synthesis of (-)-Galanthamine", Trost, B.M.; Tang, W. Angew. Chem. Int. Ed. (2002) 41, 2795. 683. "Effect of Ligand Structure on thezinc Catalyzed Henry Reaction. Asymmetric Syntheses of (-)-Denopamine and (-)-Arbutamine",Trost, B.M.; Yeh, V.; Ito, H.; Bremeyer, N. Org. Lett.(2002) 4, 2621. 682. "Synthesis of Novel Quaternary Amino Acids Using Molybdenum Catalyzed Asymmetric Allylic Alkylation", Trost, B.M.; Dogra, K. J. Am. Chem. Soc. (2002) 124, 7256. 681. "Chemo-, Regio-, and Enantioselective Pd-Catalyzed Allylic Alkylation of Indolocarbazole Pro-Aglycons",Trost, B.M.; Krische, M.J.; Berl, V.; Grenzer, E.M. Org. Lett. (2002) 4, 2005. 680. "A Convenient Synthetic Route to [CpRu(CH3CN)3]PF6", Trost, B.M.; Older, C.M. Organometallics (2002) 21, 2544. 679. "Formation of Vinyl Halides via a Ruthenium Catalyzed Three Component Coupling", Trost, B.M.; Pinkerton, A.B. J. Am. Chem. Soc. (2002) 124, 7376. 678. "Designed Ligands as Probes of the Catalytic Binding Mode in Mo Catalyzed Asymmetric Allylic Alkylation", Trost, B.M.; Dogra, K.; Hachiya, I.; Emura, T.; Hughes, D.L.; Krska, S.; Reamer, R.A.; Palucki, M.; Yasuda, N.; Reider, P.J. Angew. Chem. Int. Ed. (2002) 41, 1929. 677. "A Stereospecific Ru Catalyzed Allylic Alkylation", Trost, B.M.; Fraisse, P.; Ball, Z.T. Angew. Chem. Int. Ed. (2002) 41, 1059. 676. "A Synthesis of Trisubstituted Alkenes via a Ru Catalyzed Addition", Trost, B.M.; Shen, H.C.; Pinkerton, A.B. Chem. Eur. J. (2002) 8, 2341. 675. "An Unusual Ruthenium Catalyzed Cycloisomerization of Alkynes and Propargyl Alcohols", Trost, B.M.; Rudd, M.T. J. Am. Chem. Soc. (2002) 124, 4178. 674. "A Dinuclear Zn Catalyst for the Asymmetric Nitro-Aldol (Henry) Reaction", Trost, B.M.; Yeh, V. Angew. Chem. Int. Ed. (2002) 41, 861. 673. "On Inventing Reactions for Atom Economy", Trost, B.M. Accounts Chem. Res. (2002) 35, 695. 672. "Mechanistic Dichotemy in CpRu(CH3CN)3PF6 Catalyzed Enyne Cycloisomerizations", Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (2002) 124, 5025. 671. "Callipeltoside A: Assignment of Absolute and Relative Configuration by Total Synthesis", Trost, B.M.; Dirat, O.; Gunzner, J.L. Angew. Chem. Int. Ed. (2002) 41, 841. 670. "A Ru-Catalyzed Divergence: Oxidative Cyclization vs Cycloisomerization of bis-Homopropargylic Alcohols", Trost, B.M.; Rhee, Y,H. J. Am. Chem. Soc. (2002) 124, 2528. 669. "Atom Economy. Aldol-Type Products by Vanadium-Catalyzed Additions of Allenic Alcohols and Aldehydes", Trost, B.M.; Jonasson, C.; Wucherer, M. J. Am. Chem. Soc. (2001) 123, 12736. 668. "Markovnikov Alkyne Hydrosilylation Catalyzed by Ruthenium Complexes", Trost, B.M.; Ball, Z.T. J. Am. Chem. Soc. (2001) 123, 12726. 667. "Atom Economic Asymmetric Creation of a Quaternary Carbon. Regio- and Enantoselective Reactions of a Vinyl Epoxide with a Carbon Nucleophile", Trost, B.M.; Jiang, C. J. Am. Chem. Soc. (2001) 123, 12907. 666. "Application of the AAA Reaction to the Synthesis of the Furanoside of C-2-epi-Hygromycin A. A Total Synthesis of C-2-epi-Hygromycin A", Trost, B.M.; Dudash, J., Jr.; Dirat, O. Chem. Eur. J. (2002) 8, 259. 665. "A Synthesis of 1,1-Disubstituted Alkenes via a Ru Catalyzed Addition", Trost, B.M.; Pinkerton, A.B.; Toste, F.D.; Sperrle, M. J. Am. Chem. Soc. (2001) 123, 12504. 664. "Gem-Diacetates as Carbonyl Surrogates for Asymmetric Synthesis. Total Synthesis of Sphingofungins E and F", Trost, B.M.; Lee, C. J. Am. Chem. Soc. (2001) 123, 12191. 663. "An Enantioselective Strategy to Macrocyclic bis-Indoylmaleimides. An Efficient Formal Synthesis of LY 333531", Trost, B.M.; Tang, W. Org. Lett. (2001) 3, 3409. 662. "Pd Asymmetric Allylic Alkylation (AAA). A Powerful Synthetic Tool", Trost, B.M. Chem. Pharm. Bull. (2002) 50, 1. 661. "Ruthenium Catalyzed Two Component Addition to Form 1,3-Dienes: Optimization, Scope, Applications, and Mechanism", Trost, B.M.; Pinkerton, A.B.; Seidel, M. J. Am. Chem. Soc. (2001) 123, 12466. 660. "A Three Component Coupling Approach to Cyclopentanoids", Trost, B.M.; Pinkerton, A.B. J. Org. Chem. (2001) 66, 7714. 659. "Total Synthesis of Deschlorocallipeltoside A", Trost, B.M.; Gunzner, J.L. J. Am. Chem. Soc. (2001) 123, 9449. 658. "An Asymmetric Synthesis of C-2-epi-Hygromycin", Trost, B.M.; Dirat, O.; Dudash, J., Jr.; Hembre, E.J. Angew. Chem. Int. Ed. (2001) 40, 3658. 657. "An Unusual Ruthenium Catalyzed Dimerization of Propargyl Alcohols", Trost, B.M.; Rudd, M.T. J. Am. Chem. Soc. (2001) 123, 8862. 656. "On the Source of Stereochemical Information in Ligands for Pd Catalyzed AAA Reaction", Trost, B.M.; Zambrano, J. Synlett (2001) 907. 655. "Direct Asymmetric Aldol Reactions of Acetone Using Bimetallic Zinc Catalysts", Trost, B.M.; Silcoff, E.; Ito, H. Org. Lett. (2001) 3, 2497. 654. "Chemoselectivity in the Pd-Catalyzed Cyclization of 1,6-Enynes and Proof of the Relative Configuration of the New Stereogenic Centers", Trost, B.M.; Hashmi, A.S.K.; Ball, R.G. Adv. Syn. Catal. (2001) 343, 490. 653. "Non-Metathesis Ruthenium Catalyzed C-C Bond Formation", Trost, B.M.; Toste, F.D.; Pinkerton, A.B. Chem. Rev. (2001) 101, 2067. 652. "Constructing Tricyclic Compounds Containing a 7-Membered Ring by Ruthenium Catalyzed Intramolecular [5+2] Cycloaddition", Trost, B.M.; Shen, H.C. Angew. Chem. Int. Ed. (2001) 40, 2313. 651. "A Catalytic Asymmetric Wagner-Meerwein Shift", Trost, B.M.; Yasukata, T. J. Am. Chem. Soc. (2001) 123, 7162. 650. "An Unusual Regioselectivity in the Pd Catalyzed Cross Coupling of Alkynes. A Correction", Trost, B.M.; Gunzner, J.L.; Yasukata, T. Tetrahedron Lett. (2001) 42, 3375. 649. "AAA in KAT/DYKAT Processes. First and Second Generation Asymmetric Synthesis of (+)- and (-)-Cyclophellitol", Trost, B.M.; Patterson, D.E.; Hembre, E.J. Chem. Eur. J. (2001) 7, 1619 648. "Asymmetric Aldol Reaction via a Dinuclear Zinc Catalyst. a-Hydoxyketones as Donors", Trost, B.M.; Ito, H.; Silcoff, E. J. Am. Chem. Soc. (2001) 123, 3367. 647. "An Atom Economic Three Carbon Chain Extension to Enamides", Trost, B.M.; Surivet, J.P. Angew. Chem. Int. Ed. (2001) 40, 1468. 646. "An Atom Economical Three Carbon Chain Extension of Alkynes to Form E-Enol Silanes", Trost, B.M.; Surivet, J.-P.; Toste, F.D. J. Am. Chem. Soc. (2001) 123, 2897. 645. "Geminal-Dicarboxylates as Carbonyl Surrogates for Asymmetric Synthesis. Part II. Scope and Applications", Trost, B.M.; Lee, C.B. J. Am. Chem. Soc. (2001) 123, 3687. 644. "Geminal-Dicarboxylates as Carbonyl Surrogates for Asymmetric Synthesis. Part 1. Asymmetric Addition of Malonate Nucleophiles", Trost, B.M.; Lee, C.B. J. Am. Chem. Soc. (2001) 123, 3671. 643. "Asymmetric Induction of Conduritols via AAA Reactions. Synthesis of the Aminocyclohexitol of Hygromycin A", Trost, B.M.; Dudash, J., Jr.; Hembre, E.J. Chem. Eur. J. (2001) 7, 1619. 642. "Atom Economy. Aldol-Type Products by Vanadium Catalyzed Additions of Propargyl Alcohols and Aldehydes", Trost, B.M.; Oi, S. J. Am. Chem. Soc. (2001) 123, 1230. 641. "Synthesis of the First (1-3:6,7-h5-Cyclodecadienyl)Ruthenium Complex by the Intramolecular Reaction of Alkenes and Vinylcyclopropanes", Trost, B.M.; Toste, F.D. Angew. Chem. Int. Ed. (2001) 40, 1114. 640. "A Ruthenium Catalyzed Pyrrolidine and Piperidine Synthesis", Trost, B.M.; Pinkerton, A.B.; Kremzow, D. J. Am. Chem. Soc. (2000) 122, 12007. 639. "Asymmetric Synthesis of Quaternary Centers. Total Synthesis of (-)-Malyngolide", Trost, B.M.; Tang, W.; Schulte, J.L. Org. Lett. (2000) 2, 4013. 638. "A Direct Catalytic Enantioselective Aldol Reaction via a Novel Catalyst Design", Trost, B.M.; Ito, H. J. Am. Chem. Soc. (2000) 122, 12003. 637. "Enantoselective Total Synthesis of (-)-Galanthamine", Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (2000) 122, 11262. 636. "Atom Economical Syntheses of Oxygen Heterocycles via Tandem Palladium Catalyzed Reactions", Trost, B.M.; Frontier, A.J. J. Am. Chem. Soc. (2000) 122, 11727. 635. "Enhanced Geometrical Control in a Ru-Catalyzed Three Component Coupling", Trost, B.M.; Pinkerton, A.B. Tetrahedron Lett. (2000) 41, 9627. 634. "A Ru Catalyzed Four-Component Coupling", Trost, B.M.; Pinkerton, A.B. J. Am. Chem. Soc. (2000) 122, 8081. 633. "On the Regioselectivity of the Ru Catalyzed Intramolecular [5+2] Cycloaddition", Trost, B.M.; Shen, H.C. Org. Lett. (2000) 2, 2523. 632. "Asymmetric Alkylation of Nitroalkanes", Trost, B.M.; Surivet, J.P. Angew. Chem. Int. Ed. (2000) 39, 3122. 631. "Dynamic Kinetic Asymmetric Transformations of Diene Monoepoxides. A Practical Asymmetric Synthesis of Vinylglycinol, Vigabatrin, and Ethambutol", Trost, B.M.; Bunt, R.C.; Lemoine, R.; Calkins, T.L. J. Am. Chem. Soc. (2000) 122, 5968. 630. "a-Acetoxysulfones as "Chiral Aldehyde" Equivalents", Trost, B.M.; Crawley, M.L.; Lee, C.B. J. Am. Chem. Soc. (2000) 122, 6120. 629. "A Regioselective Ru Catalyzed Alkene-Alkyne Coupling", Trost, B.M.; Machacek, M.; Schnaderbeck, M.J. Org. Lett. (2000) 2,1761. 628. "Palladium-Catalyzed Enantioselective Synthesis of Carbanucleosides", Trost, B.M.; Madsen, R.; Guile, S.D.; Brown, B. J. Am. Chem. Soc. (2000) 122, 5947. 627. "A Ruthenium Catalyzed Hydrative Cyclization and [4+2] Cycloaddition of Yne-Enones", Trost, B.M.; Brown, R.E.; Toste, F.D J. Am. Chem. Soc. (2000) 122, 5877. 626. "Diastereo- and Enantioselective Allylation of Substituted Nitroalkanes", Trost, B.M.; Surivet, J.P. J. Am. Chem. Soc. (2000) 122, 6291. 625. "A New Strategy for Cyclopentenone Synthesis", Trost, B.M.; Pinkerton, A.B. Org. Lett. (2000) 2, 1601. 624. "Cyclic 1,2-Diketones as Building Blocks for Asymmetric Synthesis of Cycloalkenones", Trost, B.M.; Schroeder, G.M. J. Am. Chem. Soc. (2000) 122, 3785. 623. "An Asymmetric Synthesis of the Tricyclic Core and a Formal Total Synthesis of Roseophilin via an Enyne Metathesis", Trost, B.M.; Doherty, G.A. J. Am. Chem. Soc. (2000) 122, 3801. 622. "Deracemization of Baylis-Hillman Adducts", Trost, B.M.; Tsui, H.-C.; Toste, F.D J. Am. Chem. Soc. (2000) 122, 3534. 621. "Palladium Catalyzed Asymmetric Allylic Alkylation of Barbituric Acid Derivatives: Enantioselective Synthesis of Cyclopentobarbital and Pentobarbital", Trost, B.M.; Schroeder, G.M. J. Org. Chem. (2000) 65, 1569. 620. "Ruthenium Catalyzed Intramolecular [5+2] Cycloadditions", Trost, B.M.; Toste, F.D.; Shen, H. J. Am. Chem. Soc. (2000) 122, 3534. 619. "Ruthenium-Catalyzed Cycloisomerizations of 1,6- and 1,7-Enynes", Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (2000) 122, 714. 618. "Stereoselective Formation of Z-Vinyl Bromides Utilizing a Ruthenium Catalyzed Three Component Coupling", Trost, B.M.; Pinkerton, A.B. Ang. Chem. Int. Ed. (2000) 39, 360. 617. "Ruthenium-Catalyzed Cycloisomerization-Oxidation of Homopropargyl Alcohols. A New Access to gamma-Butyrolactones", Trost, B.M.; Rhee, Y.-H. J. Am. Chem. Soc. (1999) 121, 11680. 616. "A Ruthenium Catalyzed Alkylative Cycloetherification ", Trost, B.M., Pinkerton, A.B. J. Am. Chem. Soc. (1999) 121, 10842. 615. Enantioselective Allylations of Azlactones with Unsymmetrical Acyclic Allyl Esters Trost, B.M.; Ariza, X. J. Am. Chem. Soc. (1999) 121, 10727. 614. "Kinetic Dynamic Asymmetric Transformations of Conduritol B Tetracarboxylates. An Asymmetric Synthesis of D-myo-Inositol 1,4,5-Triphosphate", Trost, B.M.; Patterson, D.E.; Hembre, E.J. J. Am. Chem. Soc. (1999) 121, 10834. 613. "Regio- and Enantioselective Molybdenum Catalyzed Alkylations of Polyenyl Esters", Trost, B.M.; Hildbrand, S.; Dogra, K. J. Am. Chem. Soc. (1999) 121, 10416. 612. "A new Ru Catalyst for Alkene-Alkyne Coupling", Trost, B.M.; Toste, F.D. Tetrahedron Lett. (1999) 40, 7739. 611. "Ruthenium-Catalyzed Cycloisomerization of 1,5-Enynes Initiated by C-H Activation", Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (1999) 121, 9728. 610. "Chiral Recognition for Control of Alkene Geometry in a Transition Metal Catalyzed Allylic Alkylation", Trost, B.M.; Heinemann, C.; Ariza, X.; Weigand, S. J. Am. Chem. Soc. (1999) 121, 8667. 609. "A Total Synthesis of (+)-Saponaceolide B", Trost, B.M.; Corte, J.R. Ang. Chem. Int. Ed. (1999) 38, 3664. 608. "Towards the Total Synthesis of Saponaceolides. A Synthesis of cis-2,4-Disubstituted-3,3-dimethylmethylenecyclohexane", Trost, B.M.; Corte, J.R.; Gudiksen, M.S. Ang. Chem. Int. Ed. (1999) 38, 3662. 607. "cis-5-Amino-6-hydroxycyclohexadiene as a Chiral Building Block. An Asymmetric Synthesis of (-)-Swainsonine", Trost, B. M.; Patterson, D.E. Chem. Eur. J. (1999) 5, 3279. 606. "Inorganic Carbonates as Nucleophiles for the Asymmetric Synthesis of Vinylglycidols", Trost, B.M.; McEachern, E. J. J. Am. Chem. Soc. (1999) 121, 8649. 605. "Transition Metal-Catalyzed Asymmetric Allylic Alkylation (AAA) Reactions", Trost, B.M.; Lee, C.-B. Catalytic Asymmetric Synthesis II, I. Ojima, ed. (1999) 6759. 604. "Palladium-Catalyzed Asymmetric Alkylation of Ketone Enolates", Trost, B.M.; Schroeder, G.M. J. Am. Chem. Soc. (1999) 121, 6759. 603. An Asymmetric Synthesis of the Vitamin E Core by Pd Catalyzed Discrimination of Enantiotopic Alkenes Faces Trost, B.M.; Asakawa, N. Synthesis (1999) 1491. 602. "On the Synthesis of Z-gamma-Amino-alpha,beta-Unsaturated Esters Via Ru Catalyzed Coupling", Trost, B.M.; Roth, G.J.Organic Letters (1999) 67. 601. "A Versatile Enantioselective Strategy Towards L-C-Nucleosides; A Total Synthesis of L-Showdomycin", Trost, B.M.; Kallander, L.S. J. Org. Chem. (1999) 64, 4527. 600. "The Palladium-Catalyzed Enyne Cycloisomerization Reaction in an Asymmetric Approach to the Picrotoxane Sesquiterpenes. Part II. Second Generation Total Syntheses of Corianin, Picrotoxin, Picrotin, and Methyl Picrotoxate", Trost, B.M.; Krische, M.J. J. Am. Chem. Soc. (1999) 121, 6131. 599. "The Palladium-Catalyzed Enyne Cycloisomerization Reaction in a General Approach to the Asymmetric Synthesis of the Picrotoxane Sesquiterpenes. Part I. First Generation Total Synthesis of Corianin and Formal Syntheses of Picrotoxinin and Picrotin", Trost, B.M.; Haffner, C.; Jebaratnam, D.; Krische, M.J.; Thomas, A. J. Am. Chem. Soc. (1999) 121, 6183. 598. "Regio- and Enantioselective Allylic Alkylations of an Unsymmetrical Substrate. A Working Model" Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (1999) 121, 4545. 597. "A Ruthenium Catalyzed Two Component Addition to Form 1,3-Dienes" Trost, B.M.; Pinkerton, A.B. J. Am. Chem. Soc. (1999) 121, 4068. 596. "Palladium Catalyzed Kinetic and Dynamic Kinetic Asymmetric Transformation of 5-Acyloxy-2-(5H)-Furanone. Enantioselective Synthesis of (-)-Aflatoxin B Lactone", Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (1999) 121, 3543. 595. "A Ruthenium Catalyzed Three-Component Coupling to Form E-Vinyl Chlorides", Trost, B.M.; Pinkerton, A.B. J. Am. Chem. Soc. (1999) 121, 1988. 594. "An Asymmetric Synthesis of (-)-Anatoxin-a via an Asymmetric Cyclization Using a New Ligand for Pd Catalyzed Alkylations", Trost, B.M.; Oslob, J.D., J. Am. Chem. Soc., (1999) 121, 3057. 593. "A Two Component Catalyst System for Asymmetric Allylic Alkylations with Alcohol Pronucleophiles", Trost, B.M.; McEachern, E.; Toste, F.D. J. Am. Chem. Soc. (1998) 120, 12702. 592. "Pd Catalyzed Kinetic Resolution of Conduritol B. An Asymmetric Synthesis of (+)-Cyclophellitol", Trost, B.M.; Hembre, E.J. Tetrahedron Lett. (1998) 39, 219 591. "Novel Chiral Bidentate h5-Cyclopentadienyl-Phosphine Ligands. Their Asymmetric Induction at the Ruthenium (II) Center and Application in Catalysis", Trost, B.M.; Vidal, B.; Thommen, M. Chem. Eur. J. (1998) 4, 1055. 590. "When is a Proton Not a Proton?", Trost, B.M. Chem. Eur. J. (1998) 4, 2403. 589. "Designing Transition Metal Complexes for Molecular Recognition in Synthetic Transformations", Trost, B.M. Recent Trends in Molecular Recognition Springer accpt. (1998). 588. "Ru Catalyzed Alder Ene Type Reactions. A Formal Synthesis of Alternaric Acid", Trost, B.M.; Probst, G.; Schoop, A. J. Am. Chem. Soc. (1998) 120, 9228. 587. "A Route to Z-Enediynes via Pd Catalyzed Alkyne Additions", Trost, B.M.; Hachiya, I.; McIntosh, M.C. Tetrahedron Lett. (1998) 39, 6445. 586. "A Catalytic Enantioselective Approach to Chromans and Chromanols. A Total Synthesis of (-)Calanolides A and B and the Vitamin E Nucleus", Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (1998) 120, 9074. 585. "Transformations of the Picrotoxanes: The Synthesis of Corianin and Structural Analogues from Picrotoxinin", Krische, M.J.; Trost, B.M. Tetrahedron (1998) 54, 7109. 584. "A New Strategy for the Synthesis of Sphingosine Analogues. Sphingofungin F ", Trost, B.M.; Lee, C.B. J. Am. Chem. Soc. (1998) 120, 6818. 583. "Basic Aspects of Organic Synthesis with Transition Metals Transition Metals For Organic Synthesis", Bolm, C.; Beller, M.; eds., Trost, B.M. (1998) 3. 582. "Novel Polymer-Supported Trialkylsilanes and Their Use in Solid-Phase Organic Synthesis", Hu, Y.; Porco, J.A.; Labadie, J.W.; Gooding, O.W.; Trost, B.M. J. Org. Chem. (1998) 63, 4518. 581. "Total Synthesis of Methyl Picrotoxate via the Palladium Catalyzed Enyne Cycloisomerization Reaction", Krische, M.J.; Trost, B.M. Tetrahedron (1998) 54, 3693. 580. "Asymmetric Molybdenum Catalyzed Allylations", Trost, B.M.; Hachiya, I. J. Am. Chem. Soc. (1998) 120, 1104. 579. "Total Synthesis of (+)-Valienamine via a Strategy Derived from New Palladium Catalyzed Reactions", Trost, B.M.; Chupak, L.S.; Lübbers, T. J. Am. Chem. Soc. (1998) 120, 1732. 578. "Catalyst Controlled Diastereoselective N-Alkylations of a-Amino Esters", Trost, B.M.; Calkins, T.L.; Oertelt, C.; Zambrano, J. Tetrahedron Lett. (1998) 39, 1713. 577. "Enhanced Enantioselectivity in the Desymmetrization of meso-Biscarbamates", Trost, B.M.; Patterson, D.E. J. Org. Chem. (1998) 63, 1339. 576. "Asymmetric O- and C-Alkylation of Phenols", Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (1998) 120, 815s. 575. "On the Effect of the Nature of Ion Pairs as Nucleophiles in a Metal Catalyzed Substitution Reaction", Trost, B.M.; Bunt, R.C. J. Am. Chem. Soc. (1998) 120, 70. 574. "Molecular Gymnastics of Alkynes Orchestrated by Ruthenium Complexes", Trost, B.M. 1997 Otsuka Symposium (1997). 573. "Propargyl Alcohols as Synthons for Allenols in Conjugate Addition", Trost, B.M.; Krause, L.; Portnoy, M., J. Am. Chem. Soc., (1997) 119, 11319. 572. "Catalytic Asymmetric Alkylation of Nucleophiles. Asymmetric Synthesis of alpha-Alkylated Amino Acids", Trost, B.M.; Ariza, X., Angew. Chem. Int. Ed. Engl. (1997) 36, 2635. 571. "A Convergent Synthesis of (+) - Parviflorin, (+) - Squamocin K, and (+) - 5S-Hydroxyparviflorin", Trost, B.M.; Calkins, T.L.; Bochet, C.G., Angew. Chem. Int. Ed. Engl. (1997) 36, 2632. 570. "Transition Metal Catalyzed Cycloisomerizations", Trost, B.M.; Krische, M.J. Synlett (1998) 1, 1. 569. "Nitrogen Pronucleophiles in the Phosphine Catalyzed gamma-Addition to Methyl Butynoate", Trost, B.M.; Dake, G.R. J. Org. Chem. (1997) 62, 5670. 568. "Asymmetric Alkylation of beta-Ketoesters", Trost, B.M.; Radinov, R.; Grenzer, E.M. J. Am. Chem. Soc. (1997) 119, 7879. 567. "Nucleophilic alpha-Addition to Alkynoates. A Synthesis of Dehydroamino Acids", Trost, B.M.; Dake, G.R. J. Am. Chem. Soc. (1997) 119, 7595. 566. "On the Effect of a Cation Binding Site in an Asymmetric Ligand for a Catalyzed Nucleophilic Substitution Reaction", Trost, B.M.; Radinov, R. J. Am. Chem. Soc. (1997) 119, 5962. 565. "A Facile Cycloisomerization for the Formation of Medium and Large Rings via Allenes", Trost, B.M.; Michellys, P.-Y.; Gerusz, V.J. Angew. Chem. Int. Ed. Engl. (1997) 36, 1750. 564. "Enhancing Efficiency of a Synthetic Reaction. Palladium Catalyzed Allylic Alkylation ", Green Chemistry: Frontiers in Benign Chemical Synthesis and Processing, Anastas, P.T.; Williamson, T. eds. Chapt. 6 , pg. 101-110 (1998) Trost, B.M. 563. "The Dependence of the Pd Catalyzed Additions of Vinyl Epoxides on Pronucleophile: A Synthesis of the Macrolactam Fluviricin B1 Aglycone", Trost, B.M.; Ceschi, M.A.; König, B. Angew. Chem. Int. Ed. Engl.. (1997) 36, 1486. 562. "An Unusual Selectivity in Pd Catalyzed Cross-Coupling of Terminal Alkynes", Trost, B.M.; McIntosh, M.C. Tetrahedron Lett. (1997) 38, 3207. 561. Desymmetrization of Prochiral Diesters via Transition Metal Catalyzed Reactions Trost, B.M. Israel J. Chem. (1997), 37, 109. 560. An Enantio- and Diastereocontrolled Synthesis of (-)Neplanocin A and its 2,3-Di-Epi Isomer Trost, B.M.; Madsen, R.; Guile, S.D. Tetrahedron Lett. (1997) 38, 1707. 559. A Simple Divergence from Asymmetric Cyclopropane to Lactone Annulation Trost, B.M.; Tanimori, S.; Dunn, P.T. J. Am. Chem. Soc. (1997) 119, 2735. 558. A Ru Catalyzed Three Component Addition to Form 1,5-Diketones Trost, B.M.; Portnoy, M.; Kurihara, H J. Am. Chem. Soc. (1997) 119, 836. 557. "A Short Preparation of (S)-(E)-1-(O-Methylmandeloxy)butadiene", Trost, B.M. Chupak, L.S.; Lübbers, T. J. Org. Chem. (1997) 62, 736. 556. "Crafting Chiral Space. The Synthesis of C2 - Symmetric Diphosphine Ligands for an Outer-Sphere Catalytic Reaction", Trost, B.M.; Marschner, C. Bull. Soc. Chim. France (1997) 134, 263. 555. "An Asymmetric Synthesis of Vigabatrin", Trost, B.M.; Lemoine, R.C. Tetrahedron Letters (1996) 37, 9161. 554. "Crafting Chiral Space for a Catalytic Reaction: Allylic Alkylation", Trost, B.M. Proceedings of the Robert A. Welch Foundation - 40th Conference on Chemical Research (1997) accpt. 553. "Palladium Catalyzed Additions of Terminal Alkynes to Acceptor Alkynes", Trost, B.M.; Sorum, M.; Chan, C.; Rühter, G. J. Am. Chem. Soc. (1997) 119, 10094. 552. "Vinylcyclobutanols: A Composite Functional Group?", Trost, B.M.; Chen, D.W.C. J. Am. Chem. Soc. (1997) 119, 12541. 551. "An Asymmetric Synthesis of (-)-Epibatidine", Trost, B.M.; Cook, G.C. Tetrahedron Lett. (1996) 37, 7485. 550. "On the Diastereoselectivity of Intramolecular Pd Catalyzed TMM Cycloadditions. An Asymmetric Synthesis of the Perhydroazulene (-)-Isoclavukerin A", Trost, B.M.; Higuchi, R.I. J. Am. Chem. Soc. (1996) 118, 10094. 549. "Molecular Gymnastics of Alkynes Orchestrated by Ruthenium Complexes", Trost, B.M. Chem. Ber. (1996) 129, 1313. 548. "On the Question of Asymmetric Induction with Acyclic Allylic Substrates. An Asymmetric Synthesis of (+)-Polyoxamic Acid", Trost, B.M.; Krueger, A.C.; Bunt, R.C.; Zambrano, J. J. Am. Chem. Soc. (1996) 118, 6520. 547. "A New Catalyst for a Pd Catalyzed Alder Ene Reaction. A Total Synthesis of (+)-Cassiol ", Trost, B.M.; Li, Y. J. Am. Chem. Soc. (1996) 118, 6625. 546. "A New Pd Catalyzed Addition. A Mild Method for the Synthesis of Coumarins", Trost, B.M.; Toste, F.D. J. Am. Chem. Soc. (1996) 118, 6305. 545. "Designing a Receptor for Molecular Recognition in a Catalytic Synthetic Reaction: Allylic Alkylation", Trost, B.M. Accounts Chem. Res. (1996) 29, 355. 544. "On Asymmetric Induction in Allylic Alkylation via Enantiotopic Facial Discrimination", Trost, B.M.; Krische, M.J.; Radinov, R.; Zanoni, G. J. Am. Chem. Soc. (1996) 118, 6297. 543. "On Pd Catalyzed Cycloisomerization vs Cycloreduction. A General Strategy for Drimane Synthesis and a Short Total Synthesis of Siccanin", Trost, B.M.; Fleitz, F.J.; Watkins, W.J. J. Am. Chem. Soc. (1996) 118, 5146. 542. "Iterative Pd Catalyzed Additions for a Synthesis of Methyl 7,8,11,12-Tetradehydroretinoate", Trost, B.M.; Harms, A.E. Tetrahedron Lett. (1996) 37, 3971. 541. "Synthesis and Alkylation of Cyclopentane ß-Ketoximes Sulfones. a,a-Methylation - Alkynylation of Cyclopentanone", Trost, B.M.; Barrett, D. Tetrahedron (1996) 52, 6903. 540. "A Short Enantioselective Synthesis of Carbanucleosides", Trost, B.M.; Madsen, R.; Guile, S.D.; Elia, A.E.H. Angew. Chem. Int. Ed. Eng. (1996) 35, 1569. 539. "From Furan to Nucleosides", Trost, B.M.; Shi, Z. J. Am. Chem. Soc. (1996) 118, 3039. 538. "On the Question of the Symmetry of Formally Symmetrical -Allylpalladium Cationic Intermediates in Allylic Alkylations", Trost, B.M.; Bunt, R.C. J. Am. Chem. Soc. (1996) 118, 235. 537. "A General Strategy for the Asymmetric Synthesis of the Picrotoxanes", Trost, B.M.; Krische, M.J. J. Am. Chem. Soc. (1996) 118, 233. 536. "On Ligand Design for Outer Sphere Catalytic Reactions. A Simple Asymmetric Synthesis of Vinylglycinol", Trost, B.M.; Bunt, R.C. Angew. Chem. Int. Ed. Eng. (1996) 35, 99. 535. "Asymmetric Transition Metal Catalyzed Allylic Alkylation", Trost, B.M.; VanVranken, D.L. Chem. Rev. (1996) 96, 395. 534. "Asymmetric Introduction of Heteroatoms", Trost, B.M. Pure Appl. Chem. (1996) 68, 779. 533. "On the Flexibility of Allylic Azides as Synthetic Intermediates", Trost, B.M.; Pulley, S.R. Tetrahedron Lett. (1995) 36, 8737. 532. "An Asymmetric Total Synthesis of (+)-Pancratistatin", Trost, B.M.; Pulley, S.R. J. Am. Chem. Soc. (1995) 117, 10143. 531. "Theoretical and Experimental Studies of the Diels Alder Dimerizations of Substituted Cyclopentadienes", Froese, R.D.J.; Organ, M.G.; Goddard, J.D.; Stack, T.D.P.; Trost, B.M. J. Am. Chem. Soc. (1995) 117, 10931. 530. "A New Platform for Design of Ligands for Asymmetric Induction in Allylic Alkylations", Trost, B.M.; Breit, B.; Peukert, S.; Zambrano, J.; Ziller, J.W. Angew. Chem. Int. Ed. Eng. (1995) 34, 2386. 529. "A Two Metal Catalyst System for Redox Isomerization of Propargyl Alcohols to Enals and Enones", Trost, B.M.; Livingston, R.C. J. Am. Chem. Soc. (1995) 117, 9586. 528. "Asymmetric Synthesis of Allylic Sulfones. Useful Asymmetric Building Blocks", Trost, B.M.; Organ, M.G.; O'Doherty, G.A. J. Am. Chem. Soc. (1995) 117, 9662. 527. "Synthetic Studies to Acetogenins. The Hydroxybutenolide Terminus", Trost, B.M.; Calkins, T.L. Tetrahedron Lett. (1995) 36, 6021. 526. "An Enantioselective Synthesis of cis-4-t-Butoxycarbamoyl-1-methoxycarbonyl-2-cyclopentene. A Useful, General Buildi", Trost, B.M.; McIntosh, M.C. J. Am. Chem. Soc. (1995) 117, 7255. 524. "Asymmetric Alkylation of Allylic Gem Dicarboxylates", Trost, B.M.; Lee, C.-B.; Weiss, J.M. J. Am. Chem. Soc. (1995) 117, 7247. 523. "Nickel Catalyzed Coupling of Allyl Amines and Boronic Acids", Trost, B.M.; Spagnol, M.D. J. Chem. Soc. Perkin Trans. 1 (1995) 2083. 522. "Elaboration of Conjugated Alkenes Initiated by Insertion into a Vinylic C-H Bond", Trost, B.M.; Imi, K.; Davies, I.W. J. Am. Chem. Soc. (1995) 117, 5371. 521. "On the Pd Catalyzed Addition of Pronucleophiles to Allenes Trost, B.M.; Gerusz, V. J. Am. Chem. Soc. (1995) 117, 5156. 520. "Palladium Catalyzed Cyclopropyl-Substituted Trimethylenemethane Cycloadditions", Trost, B.M.; Parquette, J.R.; Nübling, C. Tetrahedron Lett. (1995) 36, 2917. 519. "Effect of High Pressure on a Transition Metal Catalyzed Cycloaddition", Trost, B.M.; Parquette, J.R.; Marquart, A.L. J. Am. Chem. Soc. (1995) 117, 3284. 518. "A Ru Catalyzed Synthesis of Butenolides and Pentenolides via Contra-Electronic alpha-Alkylation of Hydroxyalkynoates", Trost, B.M.; Müller, T.J.J.; Martinez, J. J. Am. Chem. Soc. (1995) 117, 1888. 517. "A Ru Catalyzed Addition of Alkenes to Alkynes", Trost, B.M.; Indolese, A.F.; Müller, T.J.J.; Treptow, B. J. Am. Chem. Soc. (1995) 117, 615. 516. "Phosphine Catalyzed Isomerization-Addition of Oxygen Nucleophiles to 2-Alkynoates", Trost, B.M.; Li, C.-J. J. Am. Chem. Soc. (1994) 116, 10819. 515. "Pd-Catalyzed Cycloaddition of Vinylcyclopentenes with Trimethylenemethane: Substituent Effect on [4+3] vs [3+2] Selectivity", Trost, B.M.; Yamazaki, S. Chem. Lett. (1994) 2245. 514. "A TMM Cycloaddition Strategy to the Bicyclo[6.3.0.]undecyl Ring System. A Total Synthesis of 11-Hydroxyjasionone", Trost, B.M.; Parquette, J.R. J. Org. Chem. (1994) 59, 7568. 513. "Deracemization of Cyclic Allyl Esters", Trost, B.M.; Organ, M.G. J. Am. Chem. Soc. (1994) 116, 10320. 512. "A Practical Synthesis of a 1,7-Enyne A - Ring Synthon En Route Toward the Total Synthesis of Vitamin D3 Analogues", Trost, B.M.; Hanson, P.R. Tetrahedron Lett. (1994) 35, 8119. 511. "Preparation of Dienylstannanes via Pd Catalyzed Regio- and Stereo-Controlled Addition Reactions", Trost, B.M.; Li, C.-J. Synthesis (1994) 1267. 510. "Atom Economy. A Challenge for Organic Synthesis - Homogeneous Catalysis Leads The Way", Trost, B.M. Angew. Chem. Int. Ed. Engl. (1995) 34, 259. 509. "A Total Synthesis of (+)-2'S,3'R-Zoapatanol", Trost, B.M.; Greenspan, P.D.; Geissler, H.; Kim, J.H.; Greeves, N. Angew. Chem. Int. Ed. Eng. (1994) 33, 2182. 508. "A Concise Convergent Strategy to Acetogenins. (+)-Solamin and Analogues", Trost, B.M.; Shi, Z. J. Am. Chem. Soc. (1994) 116, 7459. 507. "On the Nature of the Asymmetric Induction in a Palladium Catalyzed Allylic Alkylation", Trost, B.M.; Breit, B.; Organ, M.G. Tetrahedron Lett. (1994) 35, 5817. 506. "On the Use of O-Methylmandelic Acid for the Establishment of Absolute Configuration of alpha-Chiral Primary Amines", Trost, B.M.; Bunt, R.C.; Pulley, S.R. J. Org. Chem. (1994) 59, 4203. 505. "A Synthesis of the Spiroketal Subunit of (-)-Calyculin A", Trost, B.M.; Flygare, J.A. Tetrahedron Lett. (1994) 35, 4059. 504. "A Butenolide Synthesis Based Upon a Contra-Electronic Addition in a Ru Catalyzed Alder Ene Reaction. Synthesis and Absolute Configuration of (+)-Ancepsenolide", Trost, B.M.; Müller, T.J.J. J. Am. Chem. Soc. (1994) 116, 4985. 503. "Asymmetric Induction in Allylic Alkylations of 3-Acyloxycycloalkenes", Trost, B.M.; Bunt, R.C. J. Am. Chem. Soc. (1994) 116,4089. 502. "A Novel "Umpolung" in C-C Bond Formation Catalyzed by Triphenylphosphine", Trost, B.M.; Li, C.-J. J. Am. Chem. Soc. (1994) 116, 3167. 501. "Enhanced Synthetic Efficiency Towards Natural Products via Transition Metal Catalyzed Reactions", Trost, B.M. Pure Appl. Chem. (1994) 66, 2007. 500. "A Pd Catalyzed Cycloisomerization to 1,2-Dialkylidenecycloalkanes, Part II. An Alternative Catalyst System", Trost, B.M.; Romero, D.L.; Rise, F. J. Am. Chem. Soc. (1994) 116, 4268. 499. "A Pd Catalyzed Cycloisomerization to 1,2-Dialkylidenecycloalkanes, Part I", Trost, B.M.; Tanoury, G.J.; Lautens, M.; Chan, C.; MacPherson, D.T. J. Am. Chem. Soc. (1994) 116, 4255. 498. "A Cycloaddition Approach to Cyclopentenes via Metalladienes as 4p Partners", Trost, B.M.; Hashmi, A.S.K. J. Am. Chem. Soc. (1994) 116, 2183. 497. "A Synthesis of 4-Phenyl-2-phenylsulfonyl-3-vinylcyclopentanone via Palladium Catalyzed 1,3-Oxygen-to-Carbon Alkyl Shift", Lee, P.H.; Kim, J.J.; Trost, B.M. Bull. Korean Chem. Soc. (1993) 14, 637. 496. "A Novel Cycloalkylation of 1,6- and 1,7-Enynes with Stabilized Pronucleophiles", Trost, B.M.; Zhi, L.; Imi, K. Tetrahedron Lett. (1994) 35, 1361. 495. "A Practical Synthesis of Rosefuran. Furans from Acetylenes and Allyl Alcohols", Trost, B.M.; Flygare, J.A. J. Org. Chem. (1994) 59, 1078. 494. "Asymmetric Induction in Pd Catalyzed Enyne Cycloisomerizations", Trost, B.M.; Czeskis, B.A. Tetrahedron Lett. (1994) 35, 211. 493. "Intermolecular 1,3-Dipolar Cycloadditions of Munchnones with Acetylenic Dipolarophiles: Sorting out the Regioselectivity", Coppola, B.P.; Noe, M.; Schwartz, D.J.; Il Abdon, R.L.; Trost, B.M. Tetrahedron (1994) 50, 93. |
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