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Madix's Papers
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(1990-2001)
Ag(110) | Au(110) | Cu(110) | Fe(100) | Ir(110) | Ni(100) | Pd(100) | Pd(111) | Pt(110) | Pt(111)

Microscopy © copyright material for private use only ©Back to top
  1. W.W. Crew and R.J. Madix, "Monitoring Surface Reactions with Scanning Tunneling Microscopy: CO Oxidation on p(2x1)-O Pre-covered Cu(110) at 400 K, Surf. Sci. Ltrs. 319 (1994) L34.
  2. W.W. Crew and R.J. Madix, "A Varable Temperature UHV STM for Monitoring Reactions on Surfaces," Rev. of Sci. Instr. 66 (1995) 4552.
  3. X.-C. Guo and R.J. Madix, "Monolayer structure of phenoxy species on Cu(110): An STM study," Surf. Sci. 341 (1995) L1065.
  4. W.W. Crew and R.J. Madix,"A Scanning Tunneling Microscopy Study of the Oxidation of CO on Cu(110) at 400K: Site Specificity and Reaction Kinetics," Surf. Sci., 349 (1996) 275.
  5. W.W. Crew and R.J. Madix, "CO Oxidation on Oxygen Precovered Cu(110) at 150 K: Reactivity of Two Types of Atomic Oxygen Determined by STM," Surf. Sci., 356 (1996) 1.
  6. X.-C. Guo and R. J. Madix, "Site-Specific Reactivity of Oxygen at Cu(110) StepDefects: An STM Study of Ammonia Dehydrogenation," Surf. Sci., 367 (1996) L95.
  7. X.-C. Guo and R. J. Madix, "Atom-resolved Investigation of Surface Reactions: Ammonia and Oxygen on Cu(110) at 300 and 400 K," The Royal Society of Chemistry, Faraday Discussion 105, (1996) 139.
  8. X.-C. Guo and R. J. Madix, "In-Situ STM Imaging of NH3 + O Reaction on Cu(110): The Reactivity of Preadsorbed and Steady-State Oxygen," Surf. Sci., 387 (1997) 1.
  9. X.-C. Guo and Robert J. Madix, "Nonuniform Product Inhibition in Surface Reactions: Spatial Organization Effects in Ammonia Oxydehydrogenation on Cu(110)," J. Chem.Soc., Faraday Trans, 93 (23) (1997) 4197.
  10. R. J. Madix, W.W. Crew, and X.-C.Guo, "Chemical Reactions on Solid Surfaces: Atomistic Observations by Scanning Tunneling," Applied Surface Science, 113/114 (1997) 539.
  11. X.-C. Guo, R.J. Madix, "CO2 + O on Ag(110): Stoichiometry of Carbonate Formation, Reactivity of Carbonate with CO, and Reconstruction-Stabilized Chemisorption of CO2", J. Phys. Chem. B., 105, (2001) 3878.
  12. N. Hartmann, R.J. Madix, "Growth and Ordering of Cu-O Islands During Oxygen Adsorption on Cu(110) at 470 K", Surf. Sci. 488 (2001) 107.
  13. X.-C. Guo, R.J. Madix, "Carbonate on Ag(110): A Complex System Clarified by STM", Surf. Sci. 489 (2001) 37.
  14. X.-C. Guo, R.J. Madix, "Microscopic Studies of NO­2 on Ag(110)-p(2×1)-O and Reactivity of Surface Nitrate", Surf. Sci., in press, 2001.
  15. N. Hartmann, J. Biener and R.J. Madix, "Monitoring the interaction of sulfur dioxide with a TiO2(110) at 300 K by scanning tunneling microscopy", Surf. Sci. in press.
  16. X.-C. Guo, R.J. Madix, "Structural and Morphological Changes Accompanying the Reaction of Ammonia with Ag(110)-p(2x1)-O: An STM Study", Surface Science, in press, 2001.
  17. A.R. Alemozafar, X.-C. Guo, R.J. Madix, N. Hartmann, and J. Wang, "Adsorption and Reaction of Sulfur Dioxide with Ag(110)-p(2x1)-O: A LEED, TPRS, and STM Investigation", Surf. Sci. in press.
  18. A.R. Alemozafar, X.-C. Guo, and R.J. Madix, "Adsorption and Reaction of Sulfur Dioxide with Cu(110) and Cu(110)-p(2x1)-O", J. Chem. Phys. in press.
Metal OxidesBack to top
  1. Nicola J. Price, John B. Reitz, Robert J. Madix, and E. I. Solomon, "A Synchrontron XPS study of the Vanadia/Titania System as a Model for Monolayer Oxide Catalysis," Journal of Electron Spectroscopy and Related Phenomenon, 98-99 (1999) 257.
  2. Marcus Bäumer, Jürgen Biener, and Robert J. Madix, "Growth, Electronic Properties and Reactivity of Vanadium Deposited onto a Thin Alumina Film," Surface Science, 432 (1999) 189.
  3. Jürgen Biener, Marcus Bäumer, and Robert J. Madix, " A Synchrotron Study of the Deposition of Vanadia on TiO2(110)," Surface Science 432 (1999) 178.
  4. Jürgen Biener, Jiong Wang, and Robert J. Madix, "Direct Observation of the Growth of Vanadium on TiO2," Surface Science, in press.
  5. Jürgen Biener, Marcus Bäumer, P. Liu, E. Nelson, T. Kendelewisz, Gordon Brown, and Robert J. Madix, "A Synchrotron Study of the Growth of Vanadium Oxide on Al2O3(0001)," Surface Science, accepted.
  6. Jürgen Biener, Marcus Bäumer, Anders Dinger, and Robert J. Madix, "The Growth of Vanadium Oxide on Alumina and Titania Single Crystal Surfaces," Royal Society of Chemistry: J. Chem. Soc., Faraday, Discussions, 67(1999)114.
  7. Jürgen Biener, Marcus Bäumer, Robert J. Madix, P. Liu, E. Nelson, T. Kendelewisz, and Gordon Brown, "Growth and Electronic Structure of Vanadium on -Al2O3(0001)," Surface Science, 449 (2000) 50.
  8. Jürgen Biener, Marcus Bäumer, J. Wang, R.J. Madix, "Electronic Structure and Growth of Vandium on TiO2(110)," Surf, Sci., submitted.
  9. J.Wang, J.Biener, R.J.Madix, "Temperature Effects on Vanadium Overlayers on TiO2 (110)-(1x2) Surface" Surf.Sci., submitted.
  10. Q.Wang, R.J. Madix, "Preparation and Reactions of V2O5 Supported on TiO2 (110)," submitted.
DynamicsBack to top
  1. C.R. Arumainayagam, R.J. Madix, M.C. McMaster, V.M. Suzawa and J.C. Tully, "Trapping Dynamics of Xenon on Pt(111)," Surf. Sci. 226 (1990) 180.
  2. C.R. Arumainayagam, M.C. McMaster and R.J. Madix, "The Dynamics of Precursor Adsorption: Ethane on Pt(111)," Surf. Sci. Lett. 237 (1990) L424.
  3. C.R. Arumainayagam, G.R. Schoofs, M.C. McMaster and R.J. Madix, "Dynamics of Molecular Adsorption of Ethane with Pt(111): A Supersonic Molecular Beam Study," J. Phys. Chem. 95 (1991) 1041.
  4. C.R. Arumainayagam, M.C. McMaster and R.J. Madix, "Coverage Dependence of Molecular Adsorption Dynamics: Ethane on Pt(111)," J. Phys. Chem. 95 (1991) 2461.
  5. C.R. Arumainayagam, J.A. Stinnett, M.C. McMaster and R.J. Madix, "Adsorbate Induced Adsorption: Trapping Dynamics of Xe on Pt(111) at Non-Zero Coverages," J. Chem. Phys. 95 (1991) 5437.
  6. C.R. Arumainayagam and R.J. Madix, "Molecular Beam Studies of Gas-Surface Collision Dynamics," Prog. in Surf. Sci. 38 (1991) 1.
  7. M.C. McMaster and R.J. Madix, "Ethane Dissociation Dynamics on Pt(111)," Surf. Sci. 275 (1992) 265.
  8. M.C. McMaster, C.R. Arumainayagam and R.J. Madix, "Molecular Propane Adsorption Dynamics on Pt(111)," Chem. Phys., special issue, 177 (2) (1993).
  9. M.C. McMaster and R.J. Madix, "Kinetic Isotope Effect in Direct Ethane Dissociation on Pt(111)," Surf. Sci. 294 (1993) 420.
  10. M.C. McMaster S.L.M. Schroeder and R.J. Madix, "Molecular Propane Adsorption Dynamics on Pt(110)-(1x2)," Surf. Sci, 297 (1993) 253.
  11. M.C. McMaster and R.J. Madix, "Origin of Spontaneous Desorption Observed in Direct Sticking Probability Experiments of Weak Molecular Adsorption," Surf. Sci. Ltrs. 293 (1993) L847.
  12. M.C. McMaster and R.J. Madix, "Alkane Dissociation Dynamics on Pt(110)-(1x2)," J. Chem. Phys. 98 (1993) 9963.
  13. S.L.M. Schroeder, M.C. McMaster, J.A. Stinnett and R.J. Madix, "Surface Corrugation Effects on the Adsorption Dynamics of Xenon on Pt(110)-(1x2)," Surf. Sci. 297 (1993) L148.
  14. S.A. Soulen, J.A. Stinnett and R.J. Madix, "The Effect of Hydrogen on the Dynamics of the Molecular Adsorption of Ethane on Pt(111), Surf. Sci. 303 (1994) 312.
  15. S.A. Soulen and R.J. Madix, "Alkane Activation via Precursor-Mediated Dissociation on Ir(110)," Surf. Sci. 323 (1995) 1.
  16. J.A. Stinnett R.J. Madix and J.C. Tully, "Stochastic Simulations of the Trapping of Ethane on Pt(111) from a Realistic Potential. The roles of energy transfer processes and surface corrugation." J. Chem. Phys., 104 (1996) 3134.
  17. J.A. Stinnett, M.C. McMaster and R.J. Madix, "The Molecular Adsorption of Ethane on Sulfur- and Ethylidyne-Covered Surfaces of Pt(111)," Surf. Sci., 364 (1996) 325.
  18. J.A. Stinnett, M.C. McMaster, S. Schroeder, R.J. Madix and J.C. Tully, "Surface Microstructure Effects on Adsorption: Molecular Ethane Adsorption Dynamics on Pt(110)(1x2)," Surf. Sci., 365 (1996) 683.
  19. J.A. Stinnett and R.J. Madix, "Molecular Adsorption of Alkanes on Platinum Surfaces: A Predictive Theoretical Model," J. Chem. Phys., 105 (1996), 1609.
  20. James A. Stinnett, Jason F. Weaver, and R.J. Madix, "The Dynamical Origin of Non-normal Energy Scaling and the Effect of Surface Temperature on the Trapping of Low Molecular Weight Alkanes on Pt(111)," Surf. Sci., 380 (1997) 489.
  21. Jason F. Weaver and R. J. Madix, "Molecular Dynamics Simulations for Xenon Adsorption on Pt(111): Dynamical Differences in the Effects Produced by the Barker-Rettner and Morse Potentials," Surf. Sci., 391 (1997) 150.
  22. James A. Stinnett, Jason F. Weaver, and Robert J. Madix, "Surface Corrugation Effections: Molecular Ethane Adsorption Dynamics on Rigid Adsorbate-Covered Surfaces of Pt(111)," Surf. Sci., 395 (1998) 148.
  23. Jason F. Weaver, Michael A. Krzyzowski, and Robert J. Madix, "Direct Collisionally Activated and Trapping-mediated Dissociative Chemisorption of Neopentane on Clean Pt(111): the Activity of Surface Defect Sites," Surf. Sci., 393 (1997) 150.
  24. Jason F. Weaver and Robert J. Madix, "Trapping Dynamics of Isobutane, n-butane and neopentane on Pt(111): Effects of Molecular Weight and Structure," Journal of Chemical Physics, accepted.
  25. Jason F. Weaver, Michael A. Krzyzowski, and Robert J. Madix, "Direct Dissociative Chemisorption of Alkanes on Pt(111): Influence of Molecular Complexity," Journal of Chemical Physics, submitted
  26. A.F. Carlsson, R.J.Madix, "The Dynamics of Argon and Methane Trapping on Pt(111) at 30K and 50K: Energy Scaling Coverage Dependence" Surf. Sci., accepted.
  27. A.F. Carlsson, R.J. Madix, "The Trapping of Methane on Ordered Structures of CO on Pt(111)," J. Chem. Physics, accepted.
  28. A.F. Carlsson, R.J. Madix, "The Effect of Alklidyne and Atomic Oxygen Overlayers on the Adsorption of Methane on Pt(111), submitted.
  29. J.F. Weaver M. Ikai, A.F. Carlsson, R.J. Madix, "Molecular Adsorption and Growth of n-butane Adlayers on Pt(111)," submitted.
  30. A.F. Carlson, R. J. Madix, "Trapping of Ar on well ordered Ar, Kr, and Xe overlayers on Pt(111) at 30K," submitted.
  31. C. Kao, A. Carlsson, R.J. Madix, "Molecular Ethane Adsorption Dynamics on Oxygen Covered Pt (111)", submitted.
  32. A.F.Carlsson, R.J.Madix, "Alkane Trappping Onto Structured Alkane Monolayers on Pt(111) at Low Temperature," submitted.
NEXAFSBack to top
  1. P.J. Stevens, R.J. Madix and J. Stöhr, "Near-Edge Study of HCOO/ Ag(110): Evidence for Dynamic Bending," Surf. Sci. 230 (1990) 1.
  2. A.C. Liu, J. Stöhr, C.M. Friend and R.J. Madix, "A Critical Interpretation of the Near-Edge X-Ray Absorption Fine Structure of Chemisorbed Benzene," Surf. Sci. 235 (1990) 107.
  3. J.L. Solomon, R.J. Madix and J. Stöhr, "Orientation of Ethylene and Propylene on Ag(110) from NEXAFS," J. Chem. Phys. 93 (1990) 8379.
  4. J.L. Solomon, R.J. Madix, W. Wurth and J. Stöhr, "A NEXAFS and EELS Study of the Orientation of Sulfur Dioxide on Ag(110)," J. Phys. Chem. 95 (1991) 3687.
  5. J.L. Solomon, R.J. Madix and J. Stöhr, "Orientation and Absolute Coverage of Furan and 2,5-Dihydrofuran on Ag(110) Determined by NEXAFS and XPS," J. Chem. Phys. 94 (1991) 4012.
  6. J.L. Solomon, R.J. Madix and J. Stöhr, "Orientation and Absolute Coverage of Benzene, Aniline and Phenol on Ag(110) Determined by NEXAFS and XPS," Surf. Sci. 225 (1991) 12.
  7. P.A. Stevens, T.H. Upton, J. Stöhr and R.J. Madix, "Chemisorption-Induced Changes in the X-Ray-Adsorption Fine Structure of Adsorbed Species," Phys. Rev. Ltrs. 67 (1991) 1653.
ReviewBack to top
  1. C.R. Arumainayagam and R.J. Madix, "Molecular Beam Studies of Gas-Surface Collision Dynamics," Prog. in Surf. Sci. 38 (1991) 1.
  2. R.J. Madix, "Through the Labyrinth of Surface Reaction Mechanism: A Personal History 1964 - 1992," Surf. Sci. 299/300 (1994) 785.
  3. Surface Reactions, Edited by R.J. Madix. New York: Springer-Verlag, 1994.
  4. Robert J. Madix and Jeffrey T. Roberts, "The Problem of Heterogenously Catalized Partial Oxidation: Model Studies on Single Crystal Surfaces," Chapter 1, Surface Reactions, R.J. Madix (ed.), Springer-Verlag, Heidelberg, 1994.
Ag(110)Back to top
  1. John T. Gleaves, Allen G. Sault, Jerry R. Ebner and Robert J. Madix, "Ethylene Oxidation on Silver Powder: A TAP Reactor Study," J. Catalysis 121 (1990) 202.
  2. P.J. Stevens, R.J. Madix and J. Stöhr, "Near-Edge Study of HCOO/ Ag(110): Evidence for Dynamic Bending," Surf. Sci. 230 (1990) 1.
  3. D.M. Thornburg and R.J. Madix, "Cleavage of NH Bonds by Active Oxygen on Ag(110): Selective Oxidation of Ethylamine to Acetonitrile," Surf. Sci. 226 (1990) 61.
  4. Roberts J.T. and R.J. Madix, "Reactions of Weak Organic Acids with Oxygen Atoms on Ag(110): Facile and Selective Conversion of Cyclohexene to Benzene," Surf. Sci. 226 (1990) L71.
  5. J.L. Solomon, R.J. Madix and J. Stöhr, "Orientation of Ethylene and Propylene on Ag(110) from NEXAFS," J. Chem. Phys. 93 (1990) 8379.
  6. J.L. Solomon, R.J. Madix, W. Wurth and J. Stöhr, "A NEXAFS and EELS Study of the Orientation of Sulfur Dioxide on Ag(110)," J. Phys. Chem. 95 (1991) 3687.
  7. J.L. Solomon, R.J. Madix and J. Stöhr, "Orientation and Absolute Coverage of Furan and 2,5-Dihydrofuran on Ag(110) Determined by NEXAFS and XPS," J. Chem. Phys. 94 (1991) 4012.
  8. J.L. Solomon, R.J. Madix and J. Stöhr, "Orientation and Absolute Coverage of Benzene, Aniline and Phenol on Ag(110) Determined by NEXAFS and XPS," Surf. Sci. 225 (1991) 12.
  9. J.T. Roberts, A.J. Capote and R.J. Madix, "Partial Oxidation of Hydrocarbons on Silver: Conversion of 1-Butene to Maleic Anhydride by Atomically Adsorbed Oxygen on Ag(110)," Surf. Sci. 253 (1991) 13.
  10. J.T. Roberts, A.J. Capote and R.J. Madix, "Surface-Mediated Cycloaddition: 1,4-Addition of Atomically Adsorbed Oxygen to 1,3-Butadiene on Ag(110)," J. Amer. Chem. Soc. 113 (1991) 9848.
  11. D. Coulman, J.L. Solomon and R.J. Madix, "The Orientation and Electronic Structure of 1,3-Butadiene Adsorbed and Condensed on Ag(110): A NEXAFS Study," Surf. Sci. 257 (1991) 97.
  12. C.R. Ayre and R.J. Madix, "¸, ¸-Allyl, and Trimethylene-methane Complexes Derived from Isobutylene Adsorption on Oxygen-Activated Ag(110)," Surf. Sci. 262 (1992) 51.
  13. P. Merrill, and R.J. Madix, "O-H and C-H Bond Activation in Cyclohexanol by Atomic Oxygen on Ag(110): Alkoxide Formation and Selective Dehydrogenation to Cyclohexanone," Langmuir 7 (1991) 3034.
  14. R.J. Madix and J.T., Roberts, "The Coadsorption of Water and Molecular Oxygen on Ag(110): Evidence for Oxygen Desorption via Dissociation-Induced Displacement," Surf. Sci. 273 (1992) 121.
  15. J.T. Roberts, R.J. Madix and W.W. Crew, "The Rate-Limiting Step for Olefin Combustion on Silver: Experiment Compared to Theory," J. Catalysis 141 (1993) 300.
  16. W.W. Crew and R.J. Madix, "Oxidative Coupling and Ring Opening of Furan on Ag(110): Formation of Maleic Anhydride, Benzene, and Bi-furan," J. Amer. Chem. Soc. 115 (1993) 729.
  17. D.M. Jaffey and R.J. Madix, "The Reactivity of Sulfur-Containing Molecules on Noble Metal Surfaces (III): Ethanethiol on Au(110) and Ag(110)," Surf. Sci. 311 (1994) 159.
  18. C.R. Ayre and R.J. Madix, "The Adsorption and Reaction of 1,2-Propanediol on Ag(110) Under Oxygen Lean Conditions," Surf. Sci. 303 (1994) 279.
  19. C.R. Ayre and R.J. Madix, "C-C and C-H Bond Activation of 1,2-Propanedioxy by Atomic Oxygen on Ag(110): Effects of Co-adsorbed Oxygen on Surface Science," Surf. Sci. 303 (1994) 297.
  20. C.R. Ayre and R.J. Madix, "Competitive Reactions of Atomic Oxygen with Acetone on Ag(110): Nucleophilicity Versus Basicity," J. Am Chem. Soc. 117 (1995) 2301.
  21. J. Pawela-Crew, R.J. Madix, and N. Vasquez, "A Fourier Transform Infrared Study of the Repulsive Interactions and Orientation of 1-Butene and Isobutyleneon Ag(110)," Surf. Sci. 340 (1995) 119.
  22. J. Pawela-Crew, R.J. Madix and Joachim Stöhr, "The Effect of Subsurface Oxygen on the Orientation of Molecular Oxygen on Ag(110)," Surf. Sci. 339 (1995) 23.
  23. J. Pawela-Crew and R.J. Madix, "The Effect of Subsurface Oxygen on the Desorption Kinetics of Propylene Ag(110)," J. Catalysis. 153 (1995) 158.
  24. J. Pawela-Crew and R. J. Madix, "Lateral Interactions in the Desorption Kinetics of Weakly Adsorbed Species: Unexpected Differences in the Descorption of C Alkenes and Alkanes from Ag(110) due to Oriented _-Bonding of the Alkenes," Surf. Sci. 339 (1995) 8.
  25. J. Pawela-Crew and R.J. Madix, "The Effect of Weak Chemisorption of Desorption Kinetics: The Desorption of Propylene and Propane from Ag(110)," J. Chem. Phys., 104 (4) (1996) 1699.
  26. P.B. Merrill and R.J. Madix, "Aromatization of 1,3,5,7-Cyclooctatetraene and Oxydehydrogenation of cis-Cyclooctene, 1,5-Cyclooctadiene and 1,3,5,7-Cyclooctatetraene on Clean and Oxygen-precovered Ag(110)," Surf. Sci., 365 (1996) 701.
Au(110)Back to top
  1. D.M. Jaffey and R.J. Madix, "The Adsorption of Hydrogen Sulfide on Clean and Sulfided Au(110)," Surf. Sci. 258 (1991) 359.
  2. D.M. Jaffey and R.J. Madix, "The Reactivity of Sulfur-Containing Molecules on Noble Metal Surfaces (III): Ethanethiol on Au(110) and Ag(110)," Surf. Sci. 311 (1994) 159.
  3. D.M. Jaffey and R.J. Madix, "The Reactivity of Sulfur-Containing Molecules on Noble Metal Surfaces (II): t-Butyl Thiol on Au(110)," JACS 116 (1994) 3012.
  4. D.M. Jaffey and R.J. Madix, "The Reactivity of Sulfur-Containing Molecules on Noble Metal Surfaces (IV): Benzenethiol on Au(110)," JACS JACS 116 (1994) 3020.
Cu(110)Back to top
  1. R.J. Madix and S.G. Telford, "The Kinetic Isotope Effect for C-H Bond Activation on Cu(110): The Effects of Tunnelling," Surf. Sci. 277 (1992) 246.
  2. W.W. Crew and R.J. Madix, "Monitoring Surface Reactions with Scanning Tunneling Microscopy: CO Oxidation on p(2x1)-O Pre-covered Cu(110) at 400 K, Surf. Sci. Ltrs. 319 (1994) L34.
  3. R.J. Madix and S.G. Telford, "Primary and Secondary Kinetic Isotope Effects for Methoxy Dehydration and Cu(110): Absence of Tunnelling Corrections," Surf. Sci. 328 (1995) L576.
  4. Xing-Cai Guo and R.J. Madix, "Monolayer structure of phenoxy species on Cu(110): An STM study," Surf. Sci. 341 (1995) L1065.
  5. W.W. Crew and R.J. Madix,"A Scanning Tunneling Microscopy Study of the Oxidation of CO on CU(110) at 400K: Site Specificity and Reaction Kinetics," Surf. Sci., 349 (1996) 275.
  6. W.W. Crew and R.J. Madix, "CO Oxidation on Oxygen Precovered Cu(110) at 150 K: Reactivity of Two Types of Atomic Oxygen Determined by STM," Surf. Sci., 356 (1996) 1.
  7. X.-C. Guo and R. J. Madix, "Site-Specific Reactivity of Oxygen at Cu(110) StepDefects: An STM Study of Ammonia Dehydrogenation," Surf. Sci., 367 (1996) L95.
  8. X.-C. Guo and R. J. Madix, "Atom-resolved Investigation of Surface Reactions: Ammonia and Oxygen on Cu(110) at 300 and 400 K," The Royal Society of Chemistry, Faraday Discussion 105, (1996) 139.
  9. X.-C. Guo and R. J. Madix, "In-Situ STM Imaging of NH3 + O Reaction on Cu(110): The Reactivity of Preadsorbed and Steady-State Oxygen," Surf. Sci., 387 (1997) 1.
  10. X.-C. Guo and Robert J. Madix, "Nonuniform Product Inhibition in Surface Reactions: Spatial Organization Effects in Ammonia Oxydehydrogenation on Cu(110)," J. Chem.Soc., Faraday Trans, 93 (23) (1997) 4197.
  11. R. J. Madix, W.W. Crew, and X.-C.Guo, "Chemical Reactions on Solid Surfaces: Atomistic Observations by Scanning Tunneling," Applied Surface Science, 113/114 (1997) 539.
Fe(100)Back to top
  1. M.L. Burke and R.J. Madix, "Effect of CO on Hydrogen Thermal Desorption from Fe(100)," Surf. Sci. 237 (1990) 20.
  2. M.L. Burke and R.J. Madix, "Hydrogen on Pd(100)-S: The Effect of Sulfur on Precursor Mediated Adsorption and Desorption," Surf. Sci. 237 (1990) 1.
  3. M.L. Burke and R.J. Madix, "CO-Induced Ethane Formation from Ethylene and Hydrogen on Fe(100): Effects of Ligands in Surface Reactions," J. Amer. Chem. Soc. 113 (1991) 1475.
  4. M.L. Burke and R.J. Madix, "Hydrogenation and H-D Exchange Reactions of C3-C6 Substituted Alkenes on Fe(100)," J. Amer. Chem. Soc. 113 (1991) 4151.
  5. M.L. Burke and R.J. Madix, "Migratory Insertion of Ethylene into Iron-Hydrogen Bonds and ß-Hydride Elimination of Ethyl Groups on H-Covered Fe(100)," J. Amer. Chem. Soc. 113 (1991) 3675.
  6. M.L. Burke and R.J. Madix, "The Metal-Alkyl Bond Energy of the Fe(100)-C2H5 Surface Complex," JACS 114 (1992) 2780.
  7. P. Merrill and R.J. Madix, "Site Blocking by Hydrogen: CO on Clean and H-Presaturated Fe(100)," Surf. Sci. 271 (1992) 81.
  8. P.B. Merrill and R.J. Madix, "Hydrogenation of Weakly Rehybridized Ethylene on Fe(100)-H: Ethyl Group Formation," J. American Chemical Society, 118 (1996) 5062.
  9. Philip B. Merrill and R.J. Madix, "Hydrogen bonding on iron: correlation of adsorption and desorption states on Fe(100) and perturbation of the Fe-H bond with coadsorbed CO," Surf. Sci., 377 (1996) 249.
Ir(110)Back to top
  1. S.A. Soulen and R.J. Madix, "Alkane Activation via Precursor-Mediated Dissociation on Ir(110)," Surf. Sci. 323 (1995) 1.
Ni(100)Back to top
  1. N. Vasquez, Jr., A. Muscat and R.J. Madix, "The Effect of Site Distribution on the Desorption Kinetics of Carbon Monoxide from Ni(100)," Surf. Sci. 301 (1994) 83.
  2. J. Huberty and R.J. Madix, "The Determination of the Decomposition Mechanism and Kinetics of Methoxy on Clean Ni(100) and the Effects of Coadsorbed Hydrogen, CO, and Sulfur by Time Resolved Fourier Transform Infrared Spectroscopy," Surf. Sci. 334 (1995) 77.
  3. N. Vasquez, Jr., A. Muscat and R.J. Madix, "Coverage and Site Distribution Dependence of CO/Ni(100) and CO/S/Ni(100)," Surf. Sci. 339 (1995) 29
  4. Anthony Muscat and R.J. Madix, "How Annealing Affects the Desorption Kinetics of CO on Ni(100)." J. Physical Chem. 104 (1996) 3134.
  5. J. Huberty and R.J. Madix, "An FTIR Study of the Bonding of Methoxy on Ni(100): Effects of Coadsorbed Sulfur, Carbon Monoxide and Hydrogen," Surf. Sci., 360 (1996) 44.
  6. Hong Yang, Jerry Whitten, J.S. Huberty, and R.J. Madix, "Coadsorption of CO and CH3O on Ni(100)," Surf. Sci., 375 (1997) 268.
Pd(100)Back to top
  1. X.-C. Guo and R.J. Madix, "Oxygen-Activated Combustion of Alkenes on the Pd(100) Surface," JACS 117 (1995) 5523.
  2. X.-C. Guo and R.J. Madix, "Selective Hydrogenation and H-D Exchange of Unsaturated Hydrocarbons on Pd(100)-p(1x1)-H(D)," J. Catalysis. 155 (1995) 336.
  3. Xing-Cai Guo and R.J. Madix, "Dehydrogenation, Hydrogenation, Exchange, and Combustion Reactions of Aromatic Hydrocarbons on Pd(100)," J. Chem. Soc. Faraday Trans. 91 (1995) 3685.
  4. X.-C. Guo and R.J. Madix, "Hydrocarbon Combustion at High Oxygen Coverage on Palladium: A Model Study on Pd(100)," Cat. Letts., 39 (1996) 1.
  5. Xing-Cai Guo and Robert J. Madix, "Alkene Oxidation on Pd(100): Total, Not Partial," (ACS Symposium Series: Heterogeneous Hydrocarbon Oxidation) 638 (1996) 357.
  6. X.-C. Guo and Robert J. Madix, "Origin of Vinylic C-H Bond Activation in the Combustion of Alkenes on Palladium: A HREELS Study of Propene on Pd(100)-p(2x2)O," Surf. Sci. Letters, 391 (1997) L1165.
Pd(111)Back to top
  1. Tracy D. Harris and Robert J. Madix, "Alkene and Arene Combustion on Pd(111)," Journal of Catalysis, 178 (1998) 520.
  2. Natividad Vasquez, Jr. and Robert J. Madix, "Reactivity of Unsaturated Linear C6 Hydrocarbons on Pd(111) and H(D)/Pd(111)," Journal of Catalysis, 178 (1998) 234.
Pt(110)Back to top
  1. M.C. McMaster S.L.M. Schroeder and R.J. Madix, "Molecular Propane Adsorption Dynamics on Pt(110)-(1x2)," Surf. Sci, 297 (1993) 253.
  2. M.C. McMaster and R.J. Madix, "Origin of Spontaneous Desorption Observed in Direct Sticking Probability Experiments of Weak Molecular Adsorption," Surf. Sci. Ltrs. 293 (1993) L847.
  3. M.C. McMaster and R.J. Madix, "Alkane Dissociation Dynamics on Pt(110)-(1x2)," J. Chem. Phys. 98 (1993) 9963.
  4. S.L.M. Schroeder, M.C. McMaster, J.A. Stinnett and R.J. Madix, "Surface Corrugation Effects on the Adsorption Dynamics of Xenon on Pt(110)-(1x2)," Surf. Sci. 297 (1993) L148.
Pt(111)Back to top
  1. C.R. Arumainayagam, R.J. Madix, M.C. McMaster, V.M. Suzawa and J.C. Tully, "Trapping Dynamics of Xenon on Pt(111)," Surf. Sci. 226 (1990) 180.
  2. C.R. Arumainayagam, M.C. McMaster and R.J. Madix, "The Dynamics of Precursor Adsorption: Ethane on Pt(111)," Surf. Sci. Lett. 237 (1990) L424.
  3. C.R. Arumainayagam, G.R. Schoofs, M.C. McMaster and R.J. Madix, "Dynamics of Molecular Adsorption of Ethane with Pt(111): A Supersonic Molecular Beam Study," J. Phys. Chem. 95 (1991) 1041.
  4. C.R. Arumainayagam, M.C. McMaster and R.J. Madix, "Coverage Dependence of Molecular Adsorption Dynamics: Ethane on Pt(111)," J. Phys. Chem. 95 (1991) 2461.
  5. C.R. Arumainayagam, J.A. Stinnett, M.C. McMaster and R.J. Madix, "Adsorbate Induced Adsorption: Trapping Dynamics of Xe on Pt(111) at Non-Zero Coverages," J. Chem. Phys. 95 (1991) 5437.
  6. M.C. McMaster and R.J. Madix, "Ethane Dissociation Dynamics on Pt(111)," Surf. Sci. 275 (1992) 265.
  7. M.C. McMaster, C.R. Arumainayagam and R.J. Madix, "Molecular Propane Adsorption Dynamics on Pt(111)," Chem. Phys., special issue, 177 (2) (1993).
  8. M.C. McMaster and R.J. Madix, "Kinetic Isotope Effect in Direct Ethane Dissociation on Pt(111)," Surf. Sci. 294 (1993) 420.
  9. S.A. Soulen, J.A. Stinnett and R.J. Madix, "The Effect of Hydrogen on the Dynamics of the Molecular Adsorption of Ethane on Pt(111), Surf. Sci. 303 (1994) 312.
  10. M. Yata and R.J. Madix, "Kinetic Isotope Effects and Tunneling in C-H Bond Activation of Ethylene and Ethylidyne on Pt(111)," Surf. Sci. 328 (1995) 171.
  11. J.A. Stinnett R.J. Madix and J.C. Tully, "Stochastic Simulations of the Trapping of Ethane on Pt(111) from a Realistic Potential. The roles of energy transfer processes and surface corrugation." J. Chem. Phys., 104 (1996) 3134.
  12. J.A. Stinnett, M.C. McMaster and R.J. Madix, "The Molecular Adsorption of Ethane on Sulfur- and Ethylidyne-Covered Surfaces of Pt(111)," Surf. Sci., 364 (1996) 325.
  13. J.A. Stinnett, M.C. McMaster, S. Schroeder, R.J. Madix and J.C. Tully, "Surface Microstructure Effects on Adsorption: Molecular Ethane Adsorption Dynamics on Pt(110)(1x2)," Surf. Sci., 365 (1996) 683.
  14. J.A. Stinnett and R.J. Madix, "Molecular Adsorption of Alkanes on Platinum Surfaces: A Predictive Theoretical Model," J. Chem. Phys., 105 (1996), 1609.
  15. James A. Stinnett, Jason F. Weaver, and R.J. Madix, "The Dynamical Origin of Non-normal Energy Scaling and the Effect of Surface Temperature on the Trapping of Low Molecular Weight Alkanes on Pt(111)," Surf. Sci., 380 (1997) 489.
  16. Jason F. Weaver and R. J. Madix, "Molecular Dynamics Simulations for Xenon Adsorption on Pt(111): Dynamical Differences in the Effects Produced by the Barker-Rettner and Morse Potentials," Surf. Sci., 391 (1997) 150.
  17. James A. Stinnett, Jason F. Weaver, and Robert J. Madix, "Surface Corrugation Effections: Molecular Ethane Adsorption Dynamics on Rigid Adsorbate-Covered Surfaces of Pt(111)," Surf. Sci., 395 (1998) 148.
  18. Jason F. Weaver, Michael A. Krzyzowski, and Robert J. Madix, "Direct Collisionally Activated and Trapping-mediated Dissociative Chemisorption of Neopentane on Clean Pt(111): the Activity of Surface Defect Sites," Surf. Sci., 393 (1997) 150.
  19. Jason F. Weaver and Robert J. Madix, "Trapping Dynamics of Isobutane, n-butane and neopentane on Pt(111): Effects of Molecular Weight and Structure," Journal of Chemical Physics, accepted.
  20. Jason F. Weaver, Michael A. Krzyzowski, and Robert J. Madix, "Direct Dissociative Chemisorption of Alkanes on Pt(111): Influence of Molecular Complexity," Journal of Chemical Physics, submitted
  21. A.F. Carlsson, R.J.Madix, "The Dynamics of Argon and Methane Trapping on Pt(111) at 30K and 50K: Energy Scaling Coverage Dependence" Surf. Sci., accepted.
  22. A.F. Carlsson, R.J. Madix, "The Trapping of Methane on Ordered Structures of CO on Pt(111)," J. Chem. Physics, accepted.
  23. A.F. Carlsson, R.J. Madix, "The Effect of Alklidyne and Atomic Oxygen Overlayers on the Adsorption of Methane on Pt(111), submitted.
  24. J.F. Weaver M. Ikai, A.F. Carlsson, R.J. Madix, "Molecular Adsorption and Growth of n-butane Adlayers on Pt(111)," submitted.
  25. A.F. Carlson, R. J. Madix, "Trapping of Ar on well ordered Ar, Kr, and Xe overlayers on Pt(111) at 30K," submitted.
  26. C. Kao, A. Carlsson, R.J. Madix, "Molecular Ethane Adsorption Dynamics on Oxygen Covered Pt (111)", submitted.
  27. A.F.Carlsson, R.J.Madix, "Alkane Trappping Onto Structured Alkane Monolayers on Pt(111) at Low Temperature," submitted.
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